2-Indan-(1Z)-ylidenemethyl-3-methyl-thiophene | 744232-99-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚满类
• 英文名称: 2-Indan-(1Z)-ylidenemethyl-3-methyl-thiophene
• 英文别名: 2-[(Z)-2,3-dihydroinden-1-ylidenemethyl]-3-methylthiophene
• CAS: 744232-99-3
• 化学式: C₁₅H₁₄S
• 分子量: 226.342
• InChiKey: UDLULLWXAFDUQF-RAXLEYEMSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  16
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-Indan-(1Z)-ylidenemethyl-3-methyl-thiophene 在 盐酸 作用下， 反应 0.67h， 生成 2-(inden-3-ylmethyl)-3-methylthiophene
  参考文献：
  名称：

  New deconjugation reaction of ( E )-1-indanylidene methylarene brought by photolysis with protic acid

  摘要：

  A new photodeconjugation reaction of (E) indanylidene methylarenes (1a-d) carried out by photolysis in the presence of protic acid are reported with 80% to >95% yields. The reaction mechanism is through the protonation of the less stable (Z) isomer to form stable indanyl cation followed by deprotonation. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.05.108
• 作为产物：
  描述：

  (E)-2-(1-indanylidenemethyl)-3-methylthiophene 反应 0.67h， 以90%的产率得到2-Indan-(1Z)-ylidenemethyl-3-methyl-thiophene
  参考文献：
  名称：

  New deconjugation reaction of ( E )-1-indanylidene methylarene brought by photolysis with protic acid

  摘要：

  A new photodeconjugation reaction of (E) indanylidene methylarenes (1a-d) carried out by photolysis in the presence of protic acid are reported with 80% to >95% yields. The reaction mechanism is through the protonation of the less stable (Z) isomer to form stable indanyl cation followed by deprotonation. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2004.05.108