Co(3,5-dimethylpyridine)2Cl2 | 15841-70-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: Co(3,5-dimethylpyridine)2Cl2
• 英文别名: Co(II)Cl2(3,5-lutidine)2；Co(3,5-lutidine)2Cl2；dichlorocobalt;3,5-dimethylpyridine
• CAS: 15841-70-0
• 化学式: C₁₄H₁₈Cl₂CoN₂
• 分子量: 344.21
• InChiKey: JYHWHCXYKCYFFR-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  cobalt(II) chloride hexahydrate 、 3,5-二甲基吡啶 以 乙醇 为溶剂， 以61.2%的产率得到Co(3,5-dimethylpyridine)2Cl2
  参考文献：
  名称：

  Synthesis and Vibrational Spectra of Metal Halide Complexes of 3,5-Lutidine in Relation to their Structures

  摘要：

  The synthesis and the results of an infrared and Raman spectroscopic study are reported for metal(II) halide 3,5-lutidine (3,5-dimethylpyridine) complexes, M(3,5L)(2)X-2, M = Cd or Zn, X = Cl, Br or I; M = Co, Cu or Hg, X = Cl or Br; M = Mn, Fe or Ni, X = Cl, 3,5L = 3.5-lutidine. Vibrational assignments are given for all the observed bands. Some structure-spectra correlations were found. For a given series of isomorphous complexes the sum of the difference of the values of the vibrational modes of 3,5-lutidine between the free ligand as liquid and the complexed ligand was found to increase in the order of the second ionization potentials of the metals. The frequency shifts were also found to depend on the halogen.

  DOI：

  10.1080/00945719708000260