Ethyl 4-amino-5-methylpyridine-3-carboxylate | 89176-29-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Ethyl 4-amino-5-methylpyridine-3-carboxylate
• CAS: 89176-29-4
• 化学式: C₉H₁₂N₂O₂
• 分子量: 180.2
• InChiKey: NSMKGPNJCOXWLH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.3
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  65.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  Ethyl 4-azido-5-methyl-3-pyridinecarboxylate 、 氢气 在 钯 作用下， 以 乙醇 为溶剂， 反应 2.0h， 以to afford 0.43 g of the title compound as a white solid的产率得到Ethyl 4-amino-5-methylpyridine-3-carboxylate
  参考文献：
  名称：

  Heterocyclic diamide invertebrate pest control agents

  摘要：

  本发明提供了式（I），其N-氧化物和适当的盐的化合物，其中A和B分别为O或S;每个J独立地为苯环，萘环系统，5-或6-成员杂环芳香环或芳香8、9或10-成员融合杂双环系统，其中每个环或环系统可以选择地用1至4个R5取代; K与两个相邻连接碳原子一起，是一个5-或6-成员杂环芳香环，可以选择地用1至3个R4取代; R1、R2、R3、R4、R5和n如本公开中所定义。还公开了一种控制无脊椎动物害虫的方法，包括将无脊椎动物害虫或其环境与式（I）的化合物，其N-氧化物或化合物的适当盐的生物有效量接触（例如，作为本文所述的组合物）。本发明还涉及一种用于控制无脊椎动物害虫的组合物，包括式（I）的化合物，其N-氧化物或化合物的适当盐的生物有效量和至少一种从表面活性剂，固体稀释剂和液体稀释剂组成的附加组分。

  公开号：

  US07560564B2

文献信息

• HETEROCYCLIC DIAMIDE INVERTEBRATE PEST CONTROL AGENTS
  申请人：E. I. du Pont de Nemours and Company

  公开号：EP1373210A1

  公开（公告）日：2004-01-02
• US7560564B2
  申请人：——

  公开号：US7560564B2

  公开（公告）日：2009-07-14
• [EN] HETEROCYCLIC DIAMIDE INVERTEBRATE PEST CONTROL AGENTS<br/>[FR] AGENTS HETEROCYCLIQUES DIAMIDE DE LUTTE CONTRE DES PARASITES INVERTEBRES
  申请人：DU PONT

  公开号：WO2002070483A1

  公开（公告）日：2002-09-12

  This invention provides compounds of Formula (I), N-oxides and suitable salts thereof, wherein A and B are independently O or S; each J is independently a phenyl ring, a naphthyl ring system, a 5- or 6-membered heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused heterobicyclic ring system wherein each ring or ring system is optionally substituted with 1 to 4 R5; K is, together with the two contiguous linking carbon atoms, a 5- or 6-membered heteroaromatic ring optionally substituted with 1 to 3 R?4; and R1 R2, R3, R4, R5¿ and n are as defined in the disclosure. Also disclosed are methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a compound of Formula (I), an N-oxide thereof or a suitable salt of the compound (e.g., as a composition described herein). This invention also pertains to a composition for controlling an invertebrate pest comprising a biologically effective amount of a compound of Formula (I), an N-oxide thereof or a suitable salt of the compound and at least one additional component selected from the group consisting of surfactants, solid diluents and liquid diluents.
• Heterocyclic diamide invertebrate pest control agents
  申请人：——

  公开号：US20040102324A1

  公开（公告）日：2004-05-27

  This invention provides compounds of Formula (I), N-oxides and suitable salts thereof, wherein A and B are independently O or S; each J is independently a phenyl ring, a naphthyl ring system, a 5- or 6-membered heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused heterobicyclic ring system wherein each ring or ring system is optionally substituted with 1 to 4 R 5 ; K is, together with the two contiguous linking carbon atoms, a 5- or 6-membered heteroaromatic ring optionally substituted with 1 to 3 R 4 ; and R 1 , R 2 , R 3 , R 4 , R 5 and n are as defined in the disclosure. Also disclosed are methods for controlling an invertebrate pest comprising contacting the invertebrate pest or its environment with a biologically effective amount of a compound of Formula (I), an N-oxide thereof or a suitable salt of the compound (e.g., as a composition described herein). This invention also pertains to a composition for controlling an invertebrate pest comprising a biologically effective amount of a compound of Formula (I), an N-oxide thereof or a suitable salt of the compound and at least one additional component selected from the group consisting of surfactants, solid diluents and liquid diluents. 1

  本发明提供了式（I）的化合物、N-氧化物及其适当的盐，其中A和B分别为O或S;每个J分别为苯环、萘环系统、5-或6-成员杂环芳香环或芳香8、9或10-成员融合杂双环系统，其中每个环或环系统可选地被1到4个R5取代；K与两个相邻的连接碳原子一起，是一个5-或6-成员杂环芳香环，可选地被1到3个R4取代；以及R1、R2、R3、R4、R5和n如本公开说明中所定义的。还公开了用式（I）的化合物、其N-氧化物或化合物的适当盐（例如，如本文所述的组成物）的生物有效量接触无脊椎动物害虫或其环境的方法。本发明还涉及一种用于控制无脊椎动物害虫的组合物，包括式（I）的化合物、其N-氧化物或化合物的适当盐的生物有效量，以及至少一种来自表面活性剂、固体稀释剂和液体稀释剂的组分。