| 177408-59-2

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 脂肪酰基
• CAS: 177408-59-2
• 化学式: C₁₄H₂₄O
• 分子量: 208.344
• InChiKey: MQWHNGDRIFEVHQ-ARJAWSKDSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.68
• 重原子数：
  15.0
• 可旋转键数：
  8.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  20.23
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  在 lithium aluminium tetrahydride 作用下， 以 二乙二醇二甲醚 为溶剂， 生成 (3E,11Z)-Tetradeca-3,11-dien-1-ol
  参考文献：
  名称：

  Sex pheromone of tomato pestScrobipalpuloides absoluta (Lepidoptera: Gelechiidae)

  摘要：

  The sex attractant of Scrobipalpuloides absoluta females is a 90:10 mixture of (3E,8Z,11Z)-3,8,11-tetradecatrien-1-yl acetate and (3E,8Z)-3,8-tetradecadien-1-yl acetate. Tetradecadienyl acetates bearing 8Z,11Z; 3E,8Z; and 3E,11Z double bonds were synthesized by stereospecific procedures; the mass spectral and gas chromatographic properties of the 3E,8Z isomer were found to be congruent with those of the tetradecadienyl acetate from S. absoluta. In wind tunnel bioassays, a 10:1 mixture of synthetic (3E,8Z,11Z)3,8,11-tetradecatrien-1-yl acetate and (3E,8Z)-3,8-tetradecadien-1-yl acetate was highly attractive to S. absoluta males. Interestingly, the presence of (8Z, 11Z)-8,11-tetradecadien-1-yl acetate (10%) inhibited the response to (3E,8Z,11Z)-3,8,11-tetradecatrien-1-yl acetate completely.

  DOI：

  10.1007/bf02033586
• 作为产物：
  描述：

  2-[((Z)-Tetradec-11-en-3-ynyl)oxy]-tetrahydro-pyran 在 dowex 50Wx₈ 作用下， 以 甲醇 为溶剂， 生成
  参考文献：
  名称：

  Sex pheromone of tomato pestScrobipalpuloides absoluta (Lepidoptera: Gelechiidae)

  摘要：

  The sex attractant of Scrobipalpuloides absoluta females is a 90:10 mixture of (3E,8Z,11Z)-3,8,11-tetradecatrien-1-yl acetate and (3E,8Z)-3,8-tetradecadien-1-yl acetate. Tetradecadienyl acetates bearing 8Z,11Z; 3E,8Z; and 3E,11Z double bonds were synthesized by stereospecific procedures; the mass spectral and gas chromatographic properties of the 3E,8Z isomer were found to be congruent with those of the tetradecadienyl acetate from S. absoluta. In wind tunnel bioassays, a 10:1 mixture of synthetic (3E,8Z,11Z)3,8,11-tetradecatrien-1-yl acetate and (3E,8Z)-3,8-tetradecadien-1-yl acetate was highly attractive to S. absoluta males. Interestingly, the presence of (8Z, 11Z)-8,11-tetradecadien-1-yl acetate (10%) inhibited the response to (3E,8Z,11Z)-3,8,11-tetradecatrien-1-yl acetate completely.

  DOI：

  10.1007/bf02033586