[Zn(thiobenzoate)2(1,3-lutidine)2]*H2O | 1312108-49-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Zn(thiobenzoate)2(1,3-lutidine)2]*H2O
• CAS: 1312108-49-8
• 化学式: C₂₈H₂₈N₂O₂S₂Zn*H₂O
• 分子量: 572.08
• InChiKey: VCDSXFCDMSFLRL-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  [Zn(thiobenzoate)2(1,3-lutidine)2]*H2O 以 neat (no solvent, solid phase) 为溶剂， 生成 zinc sulfide
  参考文献：
  名称：

  Synthesis and characterization of nanocrystalline zinc sulfide via zinc thiobenzoate-lutidine single-source precursor

  摘要：

  ZnS nanocrystals were prepared both in the form of mesoporous powder and thin films by one step thermal decomposition technique from a single-source procure (SSP) [Zn(SOCPh)(2)Lut(2)center dot H2O]. The final product was characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), N-2 adsorption-desorption isotherm, UV-Vis absorption spectroscopy and photoluminescence (PL) study. Structural analyses of the prepared ZnS revealed the formation of cubic crystallites with diameters around 5 and 10 nm for the thin films and powder materials, respectively. On the other hand, the powder form showed mesoporous nature (type IV isotherm) with an average pore diameter of 37.9 angstrom and BET specific surface area of 51.73 m(2)/g. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.093
• 作为产物：
  描述：

  水 、 硫代苯甲酸 、 3,5-二甲基吡啶 、 zinc(II) carbonate hydroxide hydrate 以 甲苯 为溶剂， 以70.5%的产率得到[Zn(thiobenzoate)2(1,3-lutidine)2]*H2O
  参考文献：
  名称：

  Synthesis and characterization of nanocrystalline zinc sulfide via zinc thiobenzoate-lutidine single-source precursor

  摘要：

  ZnS nanocrystals were prepared both in the form of mesoporous powder and thin films by one step thermal decomposition technique from a single-source procure (SSP) [Zn(SOCPh)(2)Lut(2)center dot H2O]. The final product was characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), N-2 adsorption-desorption isotherm, UV-Vis absorption spectroscopy and photoluminescence (PL) study. Structural analyses of the prepared ZnS revealed the formation of cubic crystallites with diameters around 5 and 10 nm for the thin films and powder materials, respectively. On the other hand, the powder form showed mesoporous nature (type IV isotherm) with an average pore diameter of 37.9 angstrom and BET specific surface area of 51.73 m(2)/g. (C) 2011 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.ica.2011.02.093