[Pt(cyclo-octa-1,5-diene)(SPh)2] | 62240-66-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pt(cyclo-octa-1,5-diene)(SPh)2]
• 英文别名: benzenethiolate;(1Z,5Z)-cycloocta-1,5-diene;platinum(2+)
• CAS: 62240-66-8
• 化学式: C₂₀H₂₂PtS₂
• 分子量: 521.607
• InChiKey: YSSGUCAWLYWXBC-PHFPKPIQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tris(1-cyclohepta-2,4,6-trienyl)phosphane 、 [Pt(cyclo-octa-1,5-diene)(SPh)2] 以 二氯甲烷 为溶剂， 生成 [(tri(1-cyclohepta-2,4,6-trienyl)phosphane)Pt(SPh)2)]2
  参考文献：
  名称：

  Platinum(II) and Palladium(II) Bis(chelate) Complexes Containing both Tri(1-cyclohepta-2, 4, 6-trienyl)phosphane, P(C7H7)3, and Dichalcogenolato LigandsDedicated to Professor Joachim Strähle on the Occasion of his 65th Birthday

  摘要：

  Tri(1-cyclohepta-2,4,6-trienyl)phosphane, P(C7H7)(3) ([P] when coordinated to a metal atom), was used to stabilize complexes of platinum(II) and palladium(II) with chelating dichalcogenolato ligands as [P]M(Eboolean ANDE) [E = S, boolean AND = CH2CH2, M = Pt (3a); E = S, boolean AND = 1,2-C6H4, M = Pt (5a), Pd (6a) E = S, boolean AND = C(O)C(O), M = Pt (7a), Pd (8a); E = S, Se, boolean AND = 1,2-C-2(B10H10), M = Pt (9a, 9b), Pd (10a, 10b); E = S, boolean AND = Fe-2(CO)(6), M = Pt (11a), Pd (12a)]. Starting materials in all reactions were [P]MCl2 with M = Pt (1) and Pd (2). Attempts at the synthesis of [P]M(ER)(2) with non-chelating chalcogenolato ligands were not successful. All new complexes were characterized by multinuclear magnetic resonance spectroscopy in solution (H-1, C-13, P-31, Se-77 and Pt-195 NMR), and the molecular structures of 5a and 12a were determined by X-ray analysis. Both in the solid state and in solution the ligand [P] is linked to the metal atom by the P-M bond and by eta(2)-C=C coordination of the central C=C bond of one of the C7H7 rings. In solution, intramolecular exchange between coordinated and non-coordinated C7H7 rings is observed, the exchange process being markedly faster in the case of M = Pd than for M = Pt.

  DOI：

  10.1002/1521-3749(200206)628:5<979::aid-zaac979>3.0.co;2-l
• 作为产物：
  描述：

  dichloro( 1,5-cyclooctadiene)platinum(ll) 、 thiophenolate 以 not given 为溶剂， 生成 [Pt(cyclo-octa-1,5-diene)(SPh)2]
  参考文献：
  名称：

  涉及过渡金属的反应。第十一部分。亲核试剂与二烯铂配合物的反应

  摘要：

  研究了配合物[Pt（二烯）Cl 2 ]（二烯=降冰片二烯或二环戊二烯）与亲核试剂OPr i–，NH 2 Ph，SPh –和SCN –的反应。在每种情况下，二环戊二烯配合物都会受到二烯的攻击，S-亲核试剂也会在铂上产生取代。降冰片二烯配合物和S-亲核试剂仅发生过反应，但OPr i–和NH 2会发现对有机配体的攻击这些产品与中性单齿和双齿配体的反应通常会导致桥裂反应，但在某些情况下，降冰片烯基衍生物会发生重排，变为降冰片烯系统。描述了烯基配合物与其他亲核试剂（OMe –或NHPh –）的反应，以生成双σ键的亚烷基铂配合物。

  DOI：

  10.1039/dt9760002355