[RuCl(CO)(trimethylphosphine)3(CHCHC6H4-NMe2-p)] | 1163796-03-9

• 英文名称: [RuCl(CO)(trimethylphosphine)3(CHCHC6H4-NMe2-p)]
• CAS: 1163796-03-9
• 化学式: C₂₀H₃₉ClNOP₃Ru
• 分子量: 538.98
• InChiKey: CURWONRATOYTSE-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [RuHCl(CO)(PPh₃)₃] 、 4-二甲基氨基苯乙炔 、 三甲基膦 以 四氢呋喃 、 二氯甲烷 为溶剂， 以83%的产率得到[RuCl(CO)(trimethylphosphine)3(CHCHC6H4-NMe2-p)]
  参考文献：
  名称：

  Synthesis, characterization, and substituent effects of mononuclear ruthenium complexes [RuCl(CO)(PMe3)3(CHCH-C6H4-R-p)] (R=H, CH3, OCH3, NO2, NH2, NMe2)

  摘要：

  A series of mononuclear ruthenium complexes [RuCl(CO)(PMe3)(3)(CH=CH-C6H4-R-p)] (R = H (2a), CH3 (2b), OCH3 (2c), NO2 (2d), NH2 (2e), NMe2 (2f)) has been prepared. The respective products have been characterized by elemental analyses, NMR spectrometry, and UV-Vis spectrophotometry. The structures of complexes 2c and 2d have been established by X-ray crystallography. Electrochemical studies have revealed that electron-releasing substituents facilitate monometallic ruthenium complex oxidation, and the substituent parameter values (r) show a strong linear correlation with the anodic half-wave or oxidation peak potentials of the complexes. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.01.024