(2,15-dimethyl-3,4,,8,9,13,14-hexaethyltripyrrinato)palladium(II) trifluoroacetate | 343246-98-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: (2,15-dimethyl-3,4,,8,9,13,14-hexaethyltripyrrinato)palladium(II) trifluoroacetate
• 英文别名: trifluoroacetato(3,4,8,9,13,14-hexaethyl-2,15-dimethyltripyrrinato)palladium(II)；[trifluoracetato-(3,4,8,9,13,14-hexaethyl-2,15-dimethyltripyrrinato) palladium(II)]；2,5-bis[(Z)-(3,4-diethyl-5-methylpyrrol-2-ylidene)methyl]-3,4-diethylpyrrol-1-ide;palladium(2+);2,2,2-trifluoroacetate
• CAS: 343246-98-0
• 化学式: C₃₀H₃₈F₃N₃O₂Pd
• 分子量: 636.066
• InChiKey: UANKYHBAXZNFQC-MDNKUONPSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (2,15-dimethyl-3,4,,8,9,13,14-hexaethyltripyrrinato)palladium(II) trifluoroacetate 、 sodium acetate 以 乙醚 、 水 为溶剂， 生成 (2,15-dimethyl-3,4,,8,9,13,14-hexaethyltripyrrinato)palladium(II) acetate
  参考文献：
  名称：

  Broering, Martin; Brandt, Carsten D., Journal of the Chemical Society. Dalton Transactions (2001), 2002, # 7, p. 1391 - 1395

  摘要：

  DOI：
• 作为产物：
  描述：

  3,4,8,9,13,14-hexaethyl-2,15-dimethyltripyrrin trifluoroacetate 、 palladium diacetate 在 NaCH₃COO 作用下， 以 甲醇 为溶剂， 以55%的产率得到(2,15-dimethyl-3,4,,8,9,13,14-hexaethyltripyrrinato)palladium(II) trifluoroacetate
  参考文献：
  名称：

  Tripyrrin—the missing link in the series of oligopyrrolic ligands

  摘要：

  制备了迄今为止难以捉摸的三吡喃 2 的第一个衍生物，并对其进行了表征；对其三氟乙酰钯（II）配合物 7 的 X 射线结构分析表明，该配合物具有高度灵活的 N3 配体。

  DOI：

  10.1039/b009847g

文献信息

• Pseudohalogeno Complexes of Sterically Hindered Tripyrrinatopalladium (TrpyPd) Fragments
  作者：Martin Bröring、Serguei Prikhodovski、Carsten D. Brandt、Esther Cónsul Tejero

  DOI：10.1002/zaac.200600346

  日期：2007.3

  Eight new pseudohalogeno complexes of sterically hindered TrpyPd fragments 4–11 have been prepared by salt metathesis in one step from known trifluoroacetates TrpyPdOAcF1–3, using sodium salts of N3, NCO, NCS, NCSe, dicyanamide (dca) and tricyanomethanide (tcm) anions. Despite the propensity of the co-ligands to bind to two or more metal centres in a bridging coordination mode all new complexes have been

  使用 N3、NCO、NCS、NCSe、双氰胺 (dca) 和三氰基甲烷 (tcm) 阴离子的钠盐，通过盐复分解一步从已知的三氟乙酸盐 TrpyPdOAcF1-3 制备了八种新的空间位阻 TrpyPd 片段 4-11 的假卤素配合物. 尽管共配体倾向于以桥接配位模式与两个或多个金属中心结合，但 NMR 光谱显示所有新配合物在溶液中基本上是单体。对 TrpyPdNCS (6)、TrpyPddca (8)、TrpyPddca (9) 和 TrpyPdtcm (10) 进行的 X 射线衍射研究揭示了固态中存在两种不同的构象异构体，一种具有螺旋扭曲的 Trpy 主链，用于 6 和 10 ，以及一个几乎平面的三吡咯，但 PdII 配位的四面体畸变，即所谓的伪平面形式，用于 8 和 9。有趣的是，螺旋形式也被红外光谱中νCN伸缩带的异常波检测到。在固态中出现两种不同构象异构体的原因似乎是晶体堆积，这主要取决于阴离子共配体的形状和
• A five coordinate Pd^IIcomplex stable in solution and in the solid state
  作者：Martin Bröring、Carsten D. Brandt

  DOI：10.1039/b305547g

  日期：——

  The treatment of the strained complex TrpyPdOAc(F) 1 with NaBAr(F), followed by the addition of trimethylphosphine, yields the stable cationic 16VE- or 18VE-complexes 3 and 4, depending on the amount of phosphane added.

  用NaBAr（F）处理应变复合物TrpyPdOAc（F）1，然后添加三甲基膦，产生稳定的阳离子16VE-或18VE-复合物3和4，具体取决于所添加的膦的量。
• Cationic (tripyrrinato)palladium(II) complexes
  作者：Martin Bröring、Carsten D. Brandt、Stephan Link

  DOI：10.1016/j.ica.2005.04.011

  日期：2005.7

  The formation of cationic palladium(II)complexes [TrpyPd(II)]X-+(-) by salt metathesis of the respective trifluoroacetates with different salts of weakly coordinating anions X- was investigated. With non-hydrolizable counterions, cationic mono- and dinuclear complexes are observed depending on the nature of the anion X- and the solvent. The mononuclear cations, which are only formed with X = BArF, most probably carry a weakly bound molecule of dichloromethane at the fourth coordination site of Pd-II. When treated with diazoalkanes, only these are sufficiently reactive to form carbene complexes. Four- and five coordinate Lewis base adducts [TrpyPd(II)L](+) with L = CH3NC, tBuNH(2), PMe3, PEt3 and PiPr(3) and [TrpyPd(II)L(2)](+) with L = PMe3 were prepared from the mononuclear cations [TrpyPd(II)]+BArF-. From structural studies it becomes apparent, that the formation of stable five coordinate Pd-II species is restricted to medium size ligands and depends on the delicate balance between the steric influence of L and the strain, which is induced on the TrpyPd(II) unit. (c) 2005 Elsevier B.V. All rights reserved.