| 55661-11-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 55661-11-5
• 化学式: C₂₆H₂₆Cl₆P₂Re₂
• 分子量: 985.572
• InChiKey: OPZKIDFTNZZNTQ-UHFFFAOYSA-H

计算性质

• 辛醇/水分配系数(LogP)：
  9.63
• 重原子数：
  36.0
• 可旋转键数：
  7.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  双(环戊二烯)钴 、 以 丙酮 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Dunbar, Kim R.; Walton, Inorganic Chemistry, 1985, vol. 24, # 1, p. 5 - 10

  摘要：

  DOI：
• 作为产物：
  描述：

  以 二氯甲烷 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Dunbar, Kim R.; Walton, Inorganic Chemistry, 1985, vol. 24, # 1, p. 5 - 10

  摘要：

  DOI：

文献信息

• Preparation and characterization of dirhenium complex anions of the type [Re2Cl7(dithioether)]− with ReRe quadruple bonds
  作者：Bruce J. Heyen、J.Gregory Jennings、Gregory L. Powell

  DOI：10.1016/0020-1693(94)04250-y

  日期：1995.2

  Two dirhenate(III) anions containing dithioether ligands and Re-Re quadruple bonds have been synthesized and characterized by X-ray crystallography. Under mild reaction conditions, both 3,6-dithiaoctane (CH3CH2SCH2CH2SCH2CH3 or dto) and 2,5-dithiahexane (CH3SCH2CH2SCH3 or dth) displace a single chloride ligand from [Re2Cl8](2-) to yield [Re2Cl7(dto)](-) and [Re2Cl7(dth)](-), respectively. The tetra-n-butylammonium (Bu(4)N) salts of these complex ions have been isolated and found to react with additional dithioether to produce the unsymmetrical compounds Re2Cl8(dto)(2) and Re2Cl5(dth)(2) with Re-Re triple bonds. The complex (Bu(4)N)[Re2Cl7(dto)] crystallizes in the triclinic space group with a = 11.299(3), b = 11.552(4), c = 14.654(4) Angstrom, alpha = 108.19(2), beta = 104.07(2), gamma = 88.65(3)degrees and Z = 2, while (Bu(4)N)[Re2Cl7(dth)] crystallizes in the monoclinic space group P2(1) with a = 10.361(2), b = 15.567(4), c = 11.663(3) Angstrom, beta = 117.01(2)degrees and Z = 2. The Re-Re bond distances are 2.248(1) and 2.257(1) Angstrom for the dto and dth complexes, respectively.