Hexaacetyl-allo-inosadiamin-1,4 | 53776-79-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: Hexaacetyl-allo-inosadiamin-1,4
• CAS: 53776-79-7
• 化学式: C₁₈H₂₆N₂O₁₀
• 分子量: 430.412
• InChiKey: UBOLJZQNLBPFAN-FLHHHQDGSA-N

反应信息

• 作为产物：
  描述：

  1,5-Di-O-tosyl-muyo-inositoltetraacetat 生成 Hexaacetyl-allo-inosadiamin-1,4
  参考文献：
  名称：

  Inositol Derivatives. 7. Azidolysis of Disulfonates ofmyo-Inositol and 1,2-O-CyclohexyIidene Derivative

  摘要：

  Reactions of azide ion with three disulfonates (1,4-, 1,5-, and 1,6-) of myo-inositol and its 1,2-O-cyclohexylidene derivative were studied. The structures of the new azido compounds thus obtained were established by PMR spectroscopy and reaction sequences. The reaction mechanisms of the neighboring-group participation reactions were discussed. Hydrogenation of the azido compounds followed by acetylation afforded the corresponding six inosadiamines as their hexaacetates: three known (allo-1,5, muco-1,3, and myo-4,5) and three hitherto unknown inosadiamines (allo-1,4, muco-1,2, and chiro-2,4).

  DOI：

  10.1246/bcsj.47.1731