Iron-catalyzed direct alkenylation of sp3(C–H) bonds via decarboxylation of cinnamic acids under ligand-free conditions
作者:Hailong Yang、Hong Yan、Peng Sun、Yan Zhu、Linhua Lu、Defu Liu、Guangwei Rong、Jincheng Mao
DOI:10.1039/c3gc37131j
日期:——
An example of highly efficient low-cost ferrocene-catalyzed decarboxylative C(sp2)âC(sp3) coupling reactions via CâH functionalization has been developed successfully. It is noteworthy that nanoparticles of Fe3O4 could be used as a reusable catalyst for 7 times in the absence of ligand.
The palladium-catalyzed reaction of γ-silylated allyl acetates with water in the presence of CsF induces a previously unprecedented 1,2-shift of a substituent on silicon to produce allylsilanes in situ. The catalytic activity of the palladium increased when using an electron-poor phosphine ligand possessing fluorinated substituents. Further investigation of the reaction revealed that the approximate
A palladium NNC-pincer complex: an efficient catalyst for allylic arylation at parts per billion levels
作者:Go Hamasaka、Fumie Sakurai、Yasuhiro Uozumi
DOI:10.1039/c4cc09726b
日期:——
Allylic arylation of allylic acetates by sodium tetraarylborates in the presence of ppb to ppm (molar) loadings of a palladium NNC-pincer complex catalyst in methanol at 50 °C gave the corresponding arylated products in excellent yields.
Synthesis of ( E )-prop-1-ene-1,3-diyldibenzene derivatives via direct decarboxylative coupling of α,β-unsaturated carboxylic acids with benzyl boronic acid pinacol ester
The first copper-catalyzed cross-coupling reaction between benzyl boronic acid pinacol ester and α,β-unsaturatedcarboxylicacids was described. The ready availability of the starting materials and excellent E selectivity make this protocol a safe and operationally convenient strategy for the efficient synthesis of (E)-prop-1-ene-1,3-diyldibenzene derivatives.
Copper-catalyzed oxidative alkenylation of C(sp<sup>3</sup>)–H bonds via benzyl or alkyl radical addition to β-nitrostyrenes
作者:Shengrong Guo、Yanqin Yuan、Jiannan Xiang
DOI:10.1039/c4nj02416h
日期:——
A new method for the preparation of (E)-β-alkylstyrene derivatives has been developed via the addition of a benzyl or alkyl radical to β-nitrostyrenes using di-tert-butyl peroxide (DTBP) as the oxidant in the presence of Cu powder catalyst. The C–H bonds in various toluene derivatives, ethers, alkanes and alcohols were successfully converted into C–C bonds to yield the corresponding (E)-β-alkylstyrene