Cu(benzimidazole)4Cl2 | 56648-22-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并咪唑类
• 英文名称: Cu(benzimidazole)4Cl2
• 英文别名: Cu(BIm)4Cl2；1H-benzimidazole;dichlorocopper
• CAS: 56648-22-7
• 化学式: C₂₈H₂₄Cl₂CuN₈
• 分子量: 607.004
• InChiKey: QIZAKCUBCDEPQE-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  7.63
• 重原子数：
  39
• 可旋转键数：
  0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  115
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  Cu(BIm)4Cl2*2H2O 以 neat (no solvent) 为溶剂， 生成 Cu(benzimidazole)4Cl2
  参考文献：
  名称：

  Effect of the condition of synthesis on the composition and structure of copper(II) complexes with benzimidazole

  摘要：

  The composition and structure of copper(II) benzimidazole complexes obtained by the reaction of CuCl2 with benzimidazole (BIm) were determined. At pH 4.5-5.5, depending on the reactant ratio, dimeric compounds with the composition Cu(BIm) 4Cl(2) center dot 2H(2)O and Cu(BIm) 2Cl(2) center dot H2O are formed. They are converted to monomers at about 200 degrees C. At pH > 8, irrespective of the reactant ratio, the polymer (Cu(OH)L)(n) is formed. The complexation of copper(II) with benzimidazole in water and aqueous dioxane was studied by potentiometry, and the stability constants of the complex compounds and their dependence on the solvent composition were determined.

  DOI：

  10.1134/s0036023610090159

文献信息

• FT-IR and XPS study of copper(II) complexes of imidazole and benzimidazole
  作者：Denis P. Drolet、David M. Manuta、Alistair J. Lees、A.D. Katnani、George J. Coyle

  DOI：10.1016/s0020-1693(00)80605-2

  日期：1988.6