| 1407159-87-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1407159-87-8
• 化学式: C₇₀H₅₈N₄O₅S₂Zn
• 分子量: 1164.78
• InChiKey: CPARPVQTOYLUHZ-PMUKZOJQSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 氰乙酸 在 哌啶 作用下， 以 氯仿 为溶剂， 反应 20.0h， 以74%的产率得到
  参考文献：
  名称：

  Effect of the bridge substitution on the efficiency of dye-sensitized solar cells

  摘要：

  We have designed and synthesized a novel D-pi-A dye based on zinc porphyrin as the donor, cyanoacrylic acid as the acceptor and trans-bis(3,4-ethylenedioxythiophene)vinylene as the bridge. Under standard global AM 1.5 solar conditions, the Zn-porphyrin-2-EDOT sensitizer based cell gave a J(SC) of 7.28 mA cm(-2), V-OC of 0.438 V was obtained with a FF of 0.514, corresponding to an overall conversion efficiency eta = 1.64%. The reasons for this low efficiency are analyzed to try to develop knowledge for future dye designing. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.09.091
• 作为产物：
  描述：

  Zn(II)-5-[4-(diethoxyphosphorylmethyl)phenyl]-10,15,20-trimesitylporphyrin 、 trans-bis(3,4-ethylenedioxythiophene)vinylene biscarbaldehyde 在 sodium hydride 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 18.25h， 以42%的产率得到
  参考文献：
  名称：

  Effect of the bridge substitution on the efficiency of dye-sensitized solar cells

  摘要：

  We have designed and synthesized a novel D-pi-A dye based on zinc porphyrin as the donor, cyanoacrylic acid as the acceptor and trans-bis(3,4-ethylenedioxythiophene)vinylene as the bridge. Under standard global AM 1.5 solar conditions, the Zn-porphyrin-2-EDOT sensitizer based cell gave a J(SC) of 7.28 mA cm(-2), V-OC of 0.438 V was obtained with a FF of 0.514, corresponding to an overall conversion efficiency eta = 1.64%. The reasons for this low efficiency are analyzed to try to develop knowledge for future dye designing. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.09.091