bis[4-phenyl-2-(thiophen-2-yl)quinoline]iridium picolinate | 1597428-04-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: bis[4-phenyl-2-(thiophen-2-yl)quinoline]iridium picolinate
• 英文别名: (4-phenyl-2-(thiophen-2-yl)quinoline)₂Ir(pic)；(TPQ)₂Ir(pic)；TPQIr；(2-thiophene-2-yl-4-phenylquinoline)Ir
• CAS: 1597428-04-0
• 化学式: C₄₄H₂₈IrN₃O₂S₂
• 分子量: 887.077
• InChiKey: PSRCIDXOUKPEOF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-吡啶甲酸 、 在 potassium carbonate 作用下， 以 乙二醇乙醚 为溶剂， 反应 8.0h， 以54%的产率得到bis[4-phenyl-2-(thiophen-2-yl)quinoline]iridium picolinate
  参考文献：
  名称：

  An electron transporting unit linked multifunctional Ir(iii) complex: a promising strategy to improve the performance of solution-processed phosphorescent organic light-emitting diodes

  摘要：

  一种基于氧代二唑的电子传输（ET）单元被连接到杂环铱（iii）配合物中，并用作溶液处理的PhOLEDs的掺杂剂，其表现出比没有ET单元的掺杂剂更好的器件性能。

  DOI：

  10.1039/c3cc49796h

文献信息

• Highly efficient solution-processed deep-red emitting heteroleptic thiophene-phenylquinoline based Ir(III) complexes for phosphorescent organic light-emitting diodes
  作者：Vijaya Gopalan Sree、Woosum Cho、Sungmin Shin、Taegyun Lee、Yeong-Soon Gal、Myungkwan Song、Sung-Ho Jin

  DOI：10.1016/j.dyepig.2017.01.004

  日期：2017.4

  New series of cyclometalated iridium(III) complexes [(TPQ)(2)Ir(pic), (TPQ)(2)Ir(pic-N-O) and (TPQ)(2)Ir(acac)] based on thiophene containing phenylquinoline main ligand (C<^>N) and three different ancillary ligands (picolinic acid, picolinic acid-N-oxide and acetylacetone) have been synthesized. Synthesized Will) complexes were characterized by H-1 NMR, C-13 NMR, mass spectroscopy and their absorption, emission, cyclic voltammetry and electroluminescence properties were steadily investigated. Herein, (TPQ)(2)Ir(pic-N-O) complex showed smaller singlet-triplet splitting energy and higher transition dipole moment from ground to excited state, thus making (TPQ)(2)Ir(pic-N-O) complex, a good candidate as a phosphorescent emitter. Phosphorescent organic light-emitting diodes (PhOLEDs) were fabricated using the Will) complexes, [(TPQ)(2)Ir(Pic), (TPQ)(2)Ir(pic-N-O) and (TPQ)(2)Ir(acac)], as deep-red emitters and devices using (TPQ)(2)Ir(-pic-N-O) achieved a maximum external quantum efficiency (EQE) of 15.42% and a current efficiency of 13.94 cd/A, whereas devices using (TPQ)(2)Ir(acac) showed a more saturated/deep-red emission with a maximum EQE of 11.45%. (C) 2017 Elsevier Ltd. All rights reserved.