氯化酞菁锰(III | 53432-32-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 异吲哚及其衍生物
• 中文名称: 氯化酞菁锰(III
• 中文别名: 酞菁氯化锰(III)
• 英文名称: Chloro[5,21-dihydro-29H,31H-phthalocyaninato(2-)-κ²N²⁹,N³¹]manganese
• 英文别名: chlorophthalocyaninato(2-)manganese(III)；(phthalocyanato)manganese(III) chloride；manganese(III) phthalocyanine chloride；chloromanganese(III) phthalocyaninate；chloro(phthalocyanato)manganese(III)；manganese(III) chlorophthalocyanine；chlorophthalocyaninatomanganese(V)；[MnPc]Cl
• CAS: 53432-32-9
• 化学式: C₃₂H₁₆ClMnN₈
• 分子量: 602.924
• InChiKey: CEQXDZKNHCUAMT-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

安全信息

• WGK Germany：
  3

反应信息

• 作为反应物：
  描述：

  氯化酞菁锰(III 在 alkali-metal cyanide 作用下， 以 水 为溶剂， 生成 [phthalocyanine Mn(CN)]n
  参考文献：
  名称：

  Hanack, Michael, Israel Journal of Chemistry, 1985, vol. 25, p. 205 - 209

  摘要：

  DOI：
• 作为产物：
  描述：

  tetra(n-butyl)ammonium chlorophtalocyaninatomanganate(II) * 0.5 acetone 在 air 作用下， 以 not given 为溶剂， 生成 氯化酞菁锰(III
  参考文献：
  名称：

  Sievertsen, S.; Moubaraki, B.; Murray, K. S., Zeitschrift fur Anorganische und Allgemeine Chemie

  摘要：

  DOI：
• 作为试剂：
  描述：

  3-phenylpropyl-3-D-sulfamate 在 silver hexafluoroantimonate 、 氯化酞菁锰(III 、 二(叔丁基羰基氧基)碘苯 作用下， 以 乙腈 、 苯 为溶剂， 生成 (±)-4-deuterio-4-phenyltetrahydro-1,2,3-oxathiazine 2,2-dioxide 、 (+/-)-4-phenyl-tetrahydro-1,2,3-oxathiazine-2,2-dioxide
  参考文献：
  名称：

  GENERAL CATALYST FOR C-H FUNCTIONALIZATION

  摘要：

  该发明提供了新型的锰催化剂，如[Mn(tBuPc)]，适用于所有类型的C(sp3)-H键（脂肪族、烯丙基、丙炔基、苄基、乙醚基）的胺化，包括强1°脂肪族C—H键，同时实现优异的化学选择性、立体特异性和高官能团耐受性。我们展示了包括选择性1°C—H键胺化在内的生物活性复合分子的晚期多样化，这些复合分子涵盖了各种C(sp3)-H键类型，如对苯二酚酸和普鲁莫铁霉素衍生物的选择性1°C—H键胺化。催化剂在反应性和选择性之间的前所未有的平衡部分归因于其C—H键胺化机制介于逐步和协同之间。

  公开号：

  US20160272662A1

文献信息

• Structure and Magnetic Properties of a Low-spin Manganese(III) Phthalocyanine Dicyanide Complex
  作者：Masaki Matsuda、Jun-Ichi Yamaura、Hiroyuki Tajima、Tamotsu Inabe

  DOI：10.1246/cl.2005.1524

  日期：2005.11

  A manganese(III) complex salt, TPP[Mn I I I (Pc)(CN) 2 ]. DCM was crystallized in dichloromethane solution (Pc = phthalocyaninato, TPP + = tetraphenylphosphonium, and DCM = dichloromethane). In the crystal, Pc molecules form a pair of one-dimensional regular chains along the c axis. The magnetic susceptibility measurement revealed Mn ions in the low-spin state (S = 1) and a spin-orbit coupling effect

  锰(III)复合盐，TPP[Mn III (Pc)(CN) 2 ]。DCM 在二氯甲烷溶液中结晶（Pc = 酞菁，TPP + = 四苯基鏻，DCM = 二氯甲烷）。在晶体中，Pc 分子沿 c 轴形成一对一维规则链。磁化率测量揭示了处于低自旋状态 (S = 1) 的 Mn 离子和由于对称配体场下角轨道矩的不完全淬灭而产生的自旋轨道耦合效应。
• Tuning the visible colour of octahedral manganese(<scp>iii</scp>) phthalocyanines <i>via</i> axial ligand exchange
  作者：Declan McKearney、Kyle MacDonald、Min Suk Kim、Vance E. Williams、Daniel B. Leznoff

  DOI：10.1039/d3dt03518b

  日期：——

  [PcMnL2]SbF6 complexes (Pc = phthalocyanine) was synthesized and structurally characterized by stripping the chloride from PcMnCl with AgSbF6 in o-dichlorobenzene and adding a range of donor ligands (L = THF, pyridine, p-dimethylaminopyridine (DMAP), Ph3PO, N-methylimidazole (MeIm), MeCN) to the resulting solution. Addition of or exposure to water where L = heterocyclic amines yielded μ-oxo complexes of the

  通过在邻二氯苯中用 AgSbF 6从 PcMnCl 中剥离氯化物并添加一系列供体配体（L = THF、吡啶、对二甲氨基吡啶），合成了一系列 [PcMnL 2 ]SbF 6配合物（Pc = 酞菁）并进行了结构表征(DMAP)、Ph 3 PO、 N-甲基咪唑(MeIm)、MeCN)加入所得溶液中。添加或暴露于水（其中L=杂环胺）产生[PcMnL] 2 O形式的μ-氧配合物，其结构特征为L=DMAP和MeIm。 [PcMnL 2 ]SbF 6配合物在有机溶剂中的溶解度增加，其中轴向配体抑制PcM配合物的特征环π−π聚集。观察到多种颜色（蓝/绿到红/紫色），Q 波段吸收（不包括 μ-oxo 物质）范围为 715–761 nm，LMCT 波段范围为 497–574 nm。配体诱导的吸收位移与其在可见光区域的相对强度的组合决定了观察到的颜色范围，并说明简单的配体交换是从 PcMnCl 生产具有多种颜色的材料的有用工具。
• Mononitrosyl- undtrans-Dinitrosyl-Komplexe von Phthalocyaninaten des Mangans und Rheniums
  作者：Melanie Göldner、Bärbel Geniffke、Andreas Franken、Keith S. Murray、Heiner Homborg

  DOI：10.1002/1521-3749(200105)627:5<935::aid-zaac935>3.0.co;2-j

  日期：2001.5

  Tetra(n-butyl)ammonium or di(triphenylphosphane)iminium nitrosylacidophthalocyaninato(2-)manganate, (cat)[Mn(NO)(X)pc(2-)] (X = ONO, NCO, N-3: cat = (Bu4N)-Bu-n, PNP) is prepared from acidophthalocyaninato(2-)manganese, [Mn(X)pc(2-)], (cat)NO2 and ((Bu4N)-Bu-n)BH4 in CH2Cl2 or from nitrosylphthalocyaninato(2-)manganese. [Mn(NO)pc(2-)] and ((Bu4N)-Bu-n)X (X = ONO, NCO, N-3, NCS) at T < 120 degreesC. respectively. [Mn(NO)(X)pc(2-)](-) dissociates in methanol. and [Mn(NO)pc2-] precipitates. Nitrito(O)phthalocyaninato(2-)manganese, (cat)NO2 and hydrogensulfide yield trans-di(nitrosyl)phthalocyaninato(2-)manganate. (trans)[Mn(NO)(2)pc(2-)](-) isolated as red violet (PNP) and ((Bu4N)-Bu-n) complex salt. Nitrosyl(triphenylphosphane oxide)phthalocyaninato(2-)manganese, [Mn(NO)(OPPh3)pc(2-)] is obtained by addition of OPPh3 to [Mn(NO)pc(2-)] at 200 degreesC. Di(triphenylphosphane)phthalocyaninato(2-)rhenium(II) and (PNP)NO2 in CH2Cl2 or in molten (PNP)NO2 and PPh3 at 100 degreesC yields green blue l-di( triphenylphosphane) iminium nitrosylnitrito(O)phthalocyaninato(2-)rhenate. (l)(PNP)[Re(NO)(ONO)pc2-]. Similarly, but with ((Bu4N)-Bu-n)NO2 red plates of tetra-(n-butyl) ammonium trans-di(nitrosyl)phthalocyaninato(2-)rhenate, ((Bu4N)-Bu-n)(trans)[Re(NO)(2)pc(2-)] is isolated. Addition of (PNP)Br or (PNP)PF6 to a concentrated solution of ((Bu4N)-Bu-n)(trans)[Re (NO)(2)pc(2-)] in pyridine precipitates (l)(PNP)(trans)[Re(NO)(2)pc(2-)]. ((Bu4N)-Bu-n)(trans)[Re(NO)(2)pc(2-)] and PPh3 at 300 degreesC yield blue green nitrosyl(triphenylphosphane oxide)phthalocyaninato(2-)rhenium, [Re(NO)(OPPh3)pc2-], that is oxidised with iodine precipitating nitrosyl(triphenylphosphane oxide)phthalocyaninato(2-)rhenium triiodide, [Re(NO)(OPPh3)pc(2-)]I-3. The crystal structures of (l)(PNP)[Mn(NO)(ONO)pc(2-)] (1), (l)(PNP)[Mn(NO)(NCO)pc(2-)] (2), (l)(PNP)(trans)[Mn(NO)(2)pc(2-)] (3),l(PNP)(trans)[Re(NO)(2)pc(2-)] (4) [Mn(NO)(OPPh3)pc(2-)] (5), [Re(NO)(OPPh3)pc(2-)] (6), and [Re(NO)(OPPh3)pc(2-)]I-3. CH2Cl2 (7) have been determined. The M-N(NO) distance varies between 1.623(12)Angstrom in 5 and 1.846(3)Angstrom in 3. The M-N-O moiety is almost linear. The UV-Vis spectra with the B band at ca. 14500 cm(-1) and the Q band at 30400 cm(-1) do not dependent significantly on the axial ligand and the metal atom and its oxidation state. N-O stretching vibrations are observed in the IR spectra between 1701 cm(-1) in 3 and 1753 cm(-1) in [Mn(NO)pc(2-)] or for the Re series between 1571 cm(-1) in 4 and 1724 cm(-1) in 7. M-N(NO) stretching and M-N-O deformation vibrations are assigned in the IR spectra and resonance Raman spectra between 486 cm(-1) in 4 and 620 cm(-1) in 1.
• Grunewald, Horst; Homborg, Heiner, Zeitschrift fur Naturforschung, B: Chemical Sciences, 1990, vol. 45, # 4, p. 483 - 489
  作者：Grunewald, Horst、Homborg, Heiner

  DOI：——

  日期：——