trans-[PtI2(cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine)2] | 1231934-68-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: trans-[PtI2(cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine)2]
• CAS: 1231934-68-1
• 化学式: C₅₂H₈₄As₄I₂O₁₆Pt
• 分子量: 1713.8
• InChiKey: SVZLRAOQUDFTKT-JBEMUEFBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  2.74
• 重原子数：
  75.0
• 可旋转键数：
  10.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.69
• 拓扑面积：
  210.4
• 氢给体数：
  0.0
• 氢受体数：
  16.0

反应信息

• 作为反应物：
  描述：

  trans-[PtI2(cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine)2] 、 甲苯 以 甲苯 为溶剂， 生成 trans-[PtI2(cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine)2]*2(toluene)
  参考文献：
  名称：

  Organic Vapor Triggered Repeatable On–Off Crystalline-State Luminescence Switching

  摘要：

  A nonporous crystalline solid consisting of an organoarsenic platinum(II) complex, i.e., a mononuclear diiodoplatinum(II) complex trans-PtI2(cis-DHDAtBu)(2) (1) with cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine (cis-DHDAtBu), shows on-off solid-state luminescence switching through reversible solvent vapor uptake and escape. The on-off switching of solid-state luminescence was achieved without changing the structure or electronic state of the organoarsenic platinum(II) complex.

  DOI：

  10.1021/ic300173t
• 作为产物：
  描述：

  trans-[PtI2(cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine)2]*2(toluene) 以 neat (no solvent) 为溶剂， 生成 trans-[PtI2(cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine)2]
  参考文献：
  名称：

  Organic Vapor Triggered Repeatable On–Off Crystalline-State Luminescence Switching

  摘要：

  A nonporous crystalline solid consisting of an organoarsenic platinum(II) complex, i.e., a mononuclear diiodoplatinum(II) complex trans-PtI2(cis-DHDAtBu)(2) (1) with cis-1,4-dihydro-1,4-dimethyl-2,3,5,6-tetrakis(tert-butoxycarbonyl)-1,4-diarsinine (cis-DHDAtBu), shows on-off solid-state luminescence switching through reversible solvent vapor uptake and escape. The on-off switching of solid-state luminescence was achieved without changing the structure or electronic state of the organoarsenic platinum(II) complex.

  DOI：

  10.1021/ic300173t

文献信息

• 1,4-Dihydro-1,4-diarsinine-Bridged Dinuclear <i>trans</i>-Dihaloplatinum(II) Complexes: Synthesis and Controlled Pt−Pt Interaction by Halogen Substitution Induced Conformational Change
  作者：Manabu Arita、Kensuke Naka、Tatsuo Shimamoto、Takashi Yumura、Akiko Nakahashi、Yasuhiro Morisaki、Yoshiki Chujo

  DOI：10.1021/om100201x

  日期：2010.11.8

  varied in a series of the present platinum(II) complexes. These observations suggest that the flexibility of the bond angles around the arsenic center is an inherent property in the present organoarsenic compounds. The intermetallic interaction was induced in the dinuclear platinum(II) “face-to-face” complex using cis-DHDAtBu by the replacement of chloride with iodide. The distance of the Pt−Pt of trans

  单核和双核反式-dichloroplatinum （II）配合物，即分别使用顺式-1的反式-PtCl 2（顺式-DHDA t Bu）2和反式，反式-Pt 2 Cl 4（顺式-DHDA t Bu）2通过五甲基环戊四胺（环）的自由基反应制得的1,4-二氢-1,4-二甲基-2,3,5,6-四（叔丁氧羰基）-1,4-二氮丙啶（顺式-DHDA t Bu）-（MeAs）5）和di-通过化学计量将顺式-双（苄腈）二氯铂化学计量加到顺式-DHDA t Bu中，单独获得仅作为炔丙基二羧酸二叔丁酯的产物。通过将KI加入反式-PtCl 2（顺式-DHDA t Bu）2和反式，反式-Pt 2 Cl 4（顺式-DHDA t Bu）2的丙酮溶液中，用碘化物代替氯化物，得到反式-PtI 2（顺式-DHDA t Bu）2和反式，反式-Pt 2我4（顺式-DHDA吨丁基）2，分别。通过1 H和13 C NMR光谱，X射线晶