[Zn(Ms6mepy)2(bipy)] | 577704-92-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: [Zn(Ms6mepy)2(bipy)]
• CAS: 577704-92-8
• 化学式: C₄₀H₄₂N₆O₄S₂Zn
• 分子量: 800.333
• InChiKey: DDEDVMVLKKGWOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2,2'-联吡啶 、 锌 、 N-(6-methylpyridin-2-yl)mesitylenesulfonamide 在 Et₄NClO₄ 作用下， 以 乙腈 为溶剂， 生成 [Zn(Ms6mepy)2(bipy)]
  参考文献：
  名称：

  Different coordinative behaviour of methyl-substituted 2-pyridylsulfonamide derivatives as ligands in zinc complexes

  摘要：

  Neutral zinc complexes [ZnL2L'] of a series of methyl-substituted N-2-pyridylsulfonamide ligands (HL) and 1,10-phenanthroline or 2,2'-bipyridine (L') have been synthesised by electrochemical oxidation of anodic zinc metal in an acetonitrile solution of the ligand and the coligand. The compounds obtained have been characterised by microanalysis, IR and H-1 NMR spectroscopy, LSI mass spectrometry studies and some of the mixed complexes by single-crystal X-ray diffraction. The crystal structures show different octahedral environments around the metal (N6 or N4O2) depending on the position of the substituent on the pyridine ring. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(03)00096-2