| 132231-85-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• CAS: 132231-85-7
• 化学式: C₃₈H₃₂O₄P₂Pt
• 分子量: 809.697
• InChiKey: ZYISGFTTYKNXBK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  6.59
• 重原子数：
  45.0
• 可旋转键数：
  6.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  36.92
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  trans-{platinum(chloro)2(2,5-dimethoxy-1-diphenylphosphino-benzene)2} 在 KI 作用下， 以 乙二醇甲醚 为溶剂， 以56%的产率得到
  参考文献：
  名称：

  Reactions of [MCl2(ppqMe2)2] (M=Pd, Pt) with I− and with CF3SO3H/I− including the synthesis and X-ray crystal structure of the palladium phosphidoxo complex [Pd2(μ-I)2{(PPh20)2H}2]

  摘要：

  The compounds [MI2(ppqMe2)2] (5: M = Pd; 6: M = Pt) have been synthesised and their thermolyses and reactions with strong acids investigated. Thermolysis of 5 in the presence of excess iodide ion caused complete decomposition of the complex whereas the corresponding reaction of 6 gave the P approximately O chelated complex [Pt(ppqMe)2] (7) in good yield. Treatment of 5 with CF3SO3H/I- facilitated the loss of the 2,5-dimethoxyphenyl substituent from each phosphine ligand and gave the iodo-bridged palladium(II) phosphidoxo complex [Pd2(mu-I)2{(PPh2O)2H}2] (8). An X-ray single crystal structural analysis of 8 is reported.

  DOI：

  10.1016/s0020-1693(00)84848-3