| 125376-09-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 125376-09-2；170127-69-2
• 化学式: C₂H₃O₂*H₂O*NpO₂
• 分子量: 346.107
• InChiKey: HNYPHUAHOFXQPC-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -2.31
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  105.77
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  生成 neptunyl(V) acetate
  参考文献：
  名称：

  Bessonov, A. A.; Grigor'ev, M. S.; Afonas'eva, T. V., Radiokhimiya, 1989, vol. 31, p. 393 - 396

  摘要：

  DOI：
• 作为产物：
  描述：

  neptunium(V) hydroxide 在 CH₃COOH 作用下， 生成
  参考文献：
  名称：

  Bessonov, A. A.; Grigor'ev, M. S.; Afonas'eva, T. V., Radiokhimiya, 1989, vol. 31, p. 393 - 396

  摘要：

  DOI：

文献信息

• Crystal Structure of Neptunium(V) Acetate [(NpO2)2(OOCCH3)2(H2O)] ⋅ 2H2O
  作者：G. B. Andreev、M. Yu. Antipin、N. A. Budantseva、N. N. Krot

  DOI：10.1007/s11173-005-0172-5

  日期：2005.11

  A new neptunium(V) complex [(NpO2)2(CH3COO)2(H2O)] ⋅ 2H2O was synthesized and its crystal structure was determined. The unit cell parameters are: a = 24.007(10) Å, b = 6.779(3) Å, c = 8.076(3) Å, space group Pnma, Z = 4, V = 1314.2(9) Å3, R = 0.049, wR(F 2) = 0.105. The crystal structure of the compound is composed of neutral [(NpO2)2(CH3COO)2(H2O)] layers and molecules of the water of crystallization. Each of the crystallographically independent neptunoyl ions performs a bidentate function thus forming a composite system of cation-cation bonds.

  一种新的镎（V）复合物[(NpO2)2(CH3COO)2(H2O)]·2 被合成，其晶体结构被确定。 晶胞参数为：a = 24.007(10) Å，b = 6.779(3) Å，c = 8.076(3) Å，空间群Pnma，Z = 4，V = 1314.2(9) Å3，R = 0.049，wR(F 2) = 0.105。 该化合物的晶体结构由中性[( )2(CH3COO)2( )]层和结晶水分子组成。 每个晶体学上独立的镎离子都执行双齿功能，从而形成阳离子-阳离子键的复合系统。
• Synthesis and study of new complex Pu(V) and Np(V) acetates
  作者：A. A. Bessonov、N. N. Krot、I. A. Charushnikova、V. I. Makarenkov

  DOI：10.1134/s1066362207030022

  日期：2007.6

  Double Pu(V) and Np(V) acetates of the compositions BaPuO2Ac3 center dot 2H(2)O and SrAnO(2)Ac(3) center dot 3H(2)O with An = Pu and Np were synthesized in a well-crystallized form. In the dry state the compounds are stable in prolonged storage and are not hygroscopic. The plutonyl(V) and neptunyl(V) salts of the similar composition are isostructural. The IR spectra of the compounds were measured, and their behavior in heating was studied.