| 94645-86-0

• 分子结构分类: 有机化合物 - 有机杂环化合物
• CAS: 94645-86-0
• 化学式: C₁₁H₇N₃O₂*Hg
• 分子量: 413.785
• InChiKey: FSOKCSJHICGLLQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  1.64
• 重原子数：
  17.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  83.73
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  mercury(II) nitrate 、 cadmium(II) chloride 、 吡啶-(2-偶氮-4)间苯二酚 以 乙醇 、 水 为溶剂， 生成 、
  参考文献：
  名称：

  Spectrophotometric studies on the simultaneous determination of cadmium and mercury with 4-(2-pyridylazo)-resorcinol

  摘要：

  A new method for direct spectrophotometric determination of cadmium with 4-(2-pyridylazo)-resorcinol is reported. Absorption maximum, molar absorptivity and Sandell's sensitivity of the 1:1 (M:L) complex are 510 nm, 2.5 x 10(5) 1 mol(-1) cm-(1) and 3.55 ng cm(-2), respectively. A linear calibration graph, is obtained up to 4.49 mug ml(-1). The zero-crossing measurement technique is found suitable for the direct measurement of the first-derivative value at the specified wavelengths. Cadmium(II) (0.42-9.2 mug ml(-1)) and mercury(II) (0.35-7.4 mug ml(-1)) in different ratios have been determined simultaneously. A critical evaluation of the proposed method is performed by statistical analysis of the experimental data. The developed method was applied to the simultaneous spectrophotometric determination of Cd and Hg in some synthetic mixtures and was found to give satisfactory results. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(01)00590-x