3-(4,5-Dimethyl-<2>thienyl)-propionsaeure | 6191-05-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: 3-(4,5-Dimethyl-<2>thienyl)-propionsaeure
• 英文别名: 3-(4,5-dimethyl-thiophen-2-yl)-propionic acid；3-(4,5-Dimethylthiophen-2-yl)propanoic acid
• CAS: 6191-05-5
• 化学式: C₉H₁₂O₂S
• 分子量: 184.259
• InChiKey: VIURSHOHBVGCTG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.2
• 重原子数：
  12
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.44
• 拓扑面积：
  65.5
• 氢给体数：
  1
• 氢受体数：
  3

文献信息

• Hetero cyclic metallocene compounds and use thereof in catalyst system for producing olefin polymers
  申请人：——

  公开号：US20030036612A1

  公开（公告）日：2003-02-20

  1 A metallocene compound of general formula (I): LGZMXp, wherein L is a divalent group, Z is a moiety of formula (II), wherein R 3 and R 4 are selected from hydrogen and hydrocarbon groups; A and B are selected from S, O or CR 5 , wherein R 5 is selected from hydrogen and hydrocarbon groups, either A or B being different from CR 5 ; G is a moiety of formula (III), wherein R 6 , R 7 , R 8 and R 9 are selected from hydrogen and hydrocarbon groups, M is an atom of a transition metal, X is selected from a halogen atom, a R 10 , OR 10 , OSO 2 CF 3 , OCOR 10 , SR 10 , NR 10 2 or PR 10 2 group, wherein the substituents R 10 is hydrogen and a hydrocarbon group; p is an integer from 0 to 3.

  一种通式为(I)的1A金属茂化合物：LGZMXp，其中L是二价基团，Z是通式(II)的一部分，其中R3和R4选择自氢和烃基团；A和B选择自S、O或CR5，其中R5选择自氢和烃基团，A或B至少有一个不同于CR5；G是通式(III)的一部分，其中R6、R7、R8和R9选择自氢和烃基团，M是一个过渡金属原子，X选择自卤素原子、R10、OR10、OSO2CF3、OCOR10、SR10、NR102或PR102基团，其中取代基R10是氢和烃基团；p是从0到3的整数。
• HETEROCYCLIC METALLOCENE COMPOUNDS AND USE THEREOF IN CATALYST SYSTEMS FOR PRODUCING OLEFIN POLYMERS
  申请人：Basell Technology Company B.V.

  公开号：EP1157027A1

  公开（公告）日：2001-11-28
• Heterocyclic metallocene compounds and use thereof in catalyst systems for producing olefin polymers
  申请人：Basell Polyolefine GmbH

  公开号：EP1854804B1

  公开（公告）日：2011-05-04
• US7112638B2
  申请人：——

  公开号：US7112638B2

  公开（公告）日：2006-09-26
• [EN] HETEROCYCLIC METALLOCENE COMPOUNDS AND USE THEREOF IN CATALYST SYSTEMS FOR PRODUCING OLEFIN POLYMERS<br/>[FR] COMPOSES DE METALLOCENE HETEROCYCLIQUES ET LEUR UTILISATION DANS DES SYSTEMES CATALYTIQUES POUR PRODUIRE DES POLYMERES D'OLEFINES
  申请人：BASELL TECHNOLOGY CO BV

  公开号：WO2001047939A1

  公开（公告）日：2001-07-05

  A metallocene compound of general formula (I): LGZMXp, wherein L is a divalent group, Z is a moiety of formula (II), wherein R?3 and R4¿ are selected from hydrogen and hydrocarbon groups; A and B are selected from S, O or CR5, wherein R5 is selected from hydrogen and hydrocarbon groups, either A or B being different from CR5; G is a moiety of formula (III), wherein R?6, R7, R8 and R9¿ are selected from hydrogen and hydrocarbon groups, M is an atom of a transition metal, X is selected from a halogen atom, a R?10, OR10, OSO¿2CF3, OCOR10, SR?10, NR10¿2 or PR102 group, wherein the substituents R10 is hydrogen and a hydrocarbon group; p is an integer from 0 to 3.