trans-[Pd(C4H4N)2(PEt3)2] | 505027-29-2

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: trans-[Pd(C4H4N)2(PEt3)2]
• 英文别名: palladium(2+);pyrrol-1-ide;triethylphosphane
• CAS: 505027-29-2
• 化学式: C₂₀H₃₈N₂P₂Pd
• 分子量: 474.903
• InChiKey: AGEDSROUXPBAIC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡咯 、 tris(triethylphosphine)ppalladium(0) 以 甲苯 为溶剂， 以30%的产率得到trans-[Pd(C4H4N)2(PEt3)2]
  参考文献：
  名称：

  Oxidative insertion into the N–H bond of carbazole, indole and pyrrole with zerovalent metals

  摘要：

  The reactions of carbazole (C12H8NH), indole (C8H6NH) and pyrrole (C4H4NH) with the zerovalent [Pt(PEt3)(3)], [Pd(PEt3)(3)] and [Ni(PEt3)(3)] gave oxidative insertion into the N-H bond, affording the corresponding hydrides of the type trans-[HM(LN)(PEt3)(2)], LN = de-protonated heterocyclic ligand; the isolated compounds for platinum were trans-[HPt(C8H6N)(PEt3)(2)] (1), trans-[HPt(C4H4N)(PEt3)(2)] (2), and for nickel trans-[HNi(C12H8N)(PEt3)(2)] (3), trans-[HNi(C8H6N)(PEt3)(2)] (4) and trans-[HNi(C4H4N)(PEt3)(2)] (5); on using palladium the corresponding hydrides were also detected in solution, however, after longer reaction time the double substituted compounds: trans-[Pd(C12H8N)(2)(PEt3)(2)] (6), trans-[Pd(C8H6N)(2)(PEt3)(2)] (7) and trans-[Pd(C4H4N)(2)(PEt3)(2)] (8) were obtained. A crystal structure is reported for 6. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-328x(02)01979-4