2-[3-(3,4-bis(2-ethylhexyloxy))phenyl]phenyl pyridine | 1205538-47-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[3-(3,4-bis(2-ethylhexyloxy))phenyl]phenyl pyridine
• 英文别名: BEPPP；2-[3-[3,4-Bis(2-ethylhexoxy)phenyl]phenyl]pyridine
• CAS: 1205538-47-1
• 化学式: C₃₃H₄₅NO₂
• 分子量: 487.726
• InChiKey: JFRJRIYRNFIKEG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.3
• 重原子数：
  36
• 可旋转键数：
  16
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.48
• 拓扑面积：
  31.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  1,2-di(2-ethylhexyloxy)-4-bromobenzene 、 3-(吡啶-2-基)苯硼酸 在 四(三苯基膦)钯 、 sodium carbonate 作用下， 以 乙二醇二甲醚 、 乙醇 、 水 为溶剂， 反应 18.0h， 以69.8%的产率得到2-[3-(3,4-bis(2-ethylhexyloxy))phenyl]phenyl pyridine
  参考文献：
  名称：

  Synthesis of a Novel Ligand Containing Phenyl Pyridine

  摘要：

  In this article, we provide a new, efficient route to synthesize 2-[3-(3,4-bis(2-ethylhexyloxy)phenyl]phenyl pyridine ligand from readily available starting materials. The target compound was obtained by a condensation reaction and Suzuki coupling reaction. Structures of compounds were demonstrated by 1H NMR, 13C NMR, and high-resolution mass spectrometry. The advantages of this synthetic route are simple operation, mild reaction conditions, and good yields.

  DOI：

  10.1080/00397910902923540

文献信息

• Synthesis of a Novel Ligand Containing Phenyl Pyridine
  作者：Mingxin Yu、Haiyan Fang、Youfeng Yue、Yenchun Chen、Showan Chen

  DOI：10.1080/00397910902923540

  日期：2009.12.15

  In this article, we provide a new, efficient route to synthesize 2-[3-(3,4-bis(2-ethylhexyloxy)phenyl]phenyl pyridine ligand from readily available starting materials. The target compound was obtained by a condensation reaction and Suzuki coupling reaction. Structures of compounds were demonstrated by 1H NMR, 13C NMR, and high-resolution mass spectrometry. The advantages of this synthetic route are simple operation, mild reaction conditions, and good yields.