bis-(N,N-dimethylformamide)bis[[(4-methylphenyl)sulfonyl]-2-pyridyl-amide]cobalt(II) | 302897-45-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis-(N,N-dimethylformamide)bis[[(4-methylphenyl)sulfonyl]-2-pyridyl-amide]cobalt(II)
• CAS: 302897-45-6
• 化学式: C₃₀H₃₆CoN₆O₆S₂
• 分子量: 699.778
• InChiKey: UUXREGMJVUXXCJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  N-(2-pyridyl)-p-toluenesulfonamide 、 钴 、 N,N-二甲基甲酰胺 在 (C₂H₅)4NClO₄ 作用下， 以 N,N-二甲基甲酰胺 、 乙腈 为溶剂， 生成 bis-(N,N-dimethylformamide)bis[[(4-methylphenyl)sulfonyl]-2-pyridyl-amide]cobalt(II)
  参考文献：
  名称：

  Direct electrochemical synthesis of cobalt(II) complexes of tosylamides: crystal structures of [CoL2py2], [CoL2DMF2], [CoL2bipy] and [CoL2phen], L=[(4-methylphenyl)sulfonyl]-2-pyridylamide

  摘要：

  Several complexes with tosylamides were synthesised by the electrochemical oxidation of cobalt in an acetonitrile solution of [(4-methylphenyl)sulfonyl]-imino-1 H-pyridine (HL) and the appropriate neutral coligand: L' (pyridine, 2,2'-bipyridine, 1,10-phenanthroline or N,N-dimethylformamide). The structures of bis-(N,N-dimethylformamide)bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cobalt(II), bis-(pyridine)bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cobalt(II), 2,2'-bipyridine bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cobalt(II) and 1,10-phenanthroline bis{[(4-methylphenyl)sulfonyl]-2-pyridyl-amide}cobalt(II) were determined by X-ray diffraction methods. In these monomeric complexes, the cobalt atom is in a distorted octahedral environment. The vibrational and electronic spectra of the complexes are discussed and are shown to agree with the structures. (C) 2000 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00437-x