[Ag(trifluoroacetate)(bis(diphenylphosphino)methane)]2 | 810662-26-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Ag(trifluoroacetate)(bis(diphenylphosphino)methane)]2
• 英文别名: [Ag(tfa)(dpam)]2
• CAS: 810662-26-1；844467-02-3
• 化学式: C₅₄H₄₄Ag₂F₆O₄P₄
• 分子量: 1210.56
• InChiKey: ADWIFOWQBWVDNK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  silver trifluoroacetate 、 双二苯基膦甲烷 以 乙醇 为溶剂， 以71%的产率得到[Ag(trifluoroacetate)(bis(diphenylphosphino)methane)]2
  参考文献：
  名称：

  Syntheses, spectroscopic and structural characterization of some (solvated) binuclear adducts of the form Ag(oxyanion):dpem(:S) (1:1(:x))2 (oxyanion=ClO4, F3CCO2, F3CSO3; dpem=Ph2E(CH2)EPh2 (E=P, As))

  摘要：

  Syntheses, spectroscopic (IR, NMR and ESI MS) and single crystal X-ray structural characterizations are reported for a wide variety of adducts of Ag(oxyanion):dpem (:S) (1:1(: n))(2) (oxyanion = ClO4, F3CCO2 (tfa) F3CSO3 ffs); dpem = Ph2E(CH2)EPh2) stoichiometry among which the basic Ag(Ph-2(CH2)EPh2)(2)Ag core is diversely perturbed by interactions with anions and solvent molecules. ESI MS and P-31 NMR spectroscopy indicated that dinuclear species also exist in solution. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ica.2004.07.032