Cyclobutanetetrone, 1,3-bis(phenylhydrazone) | 143033-67-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Cyclobutanetetrone, 1,3-bis(phenylhydrazone)
• 英文别名: cyclobutanetetraone 1,3-bis(phenylhydrazone)
• CAS: 143033-67-4
• 化学式: C₁₆H₁₂N₄O₂
• 分子量: 292.297
• InChiKey: MUHQAUYTWCOYMJ-LRVMPXQBSA-N

物化性质

• 沸点：
  448.1±28.0 °C(Predicted)
• 密度：
  1.34±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.07
• 重原子数：
  22.0
• 可旋转键数：
  4.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  82.92
• 氢给体数：
  2.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  Cyclobutanetetrone, 1,3-bis(phenylhydrazone) 在 三乙胺 作用下， 以 氘代二甲亚砜 为溶剂， 生成 3-Oxo-2-phenylazo-4-(phenyl-hydrazono)-cyclobut-1-enol anion
  参考文献：
  名称：

  The cations and anions of cyclobutanetetraone poly(phenylhydrazones)

  摘要：

  Six cyclobutanetetraone poly(arylhydrazones) have been treated with acids and bases, and the structures of the resulting anions and cations studied by UV-Vis absorption and NMR spectroscopy. In acid media, all the hydrazones studied formed cations, which exhibited bathochromic shifts due to the extension of their resonance systems. However, in bases, only some (those which could enolize) formed anions that exhibited hypsochromic shifts; the others were unaltered. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0008-6215(01)00168-9
• 作为产物：
  描述：

  cyclobutanetetraone 、 苯肼 以 甲醇 为溶剂， 反应 0.17h， 以55%的产率得到Cyclobutanetetrone, 1,3-bis(phenylhydrazone)
  参考文献：
  名称：

  Khadem, Hassan S. El; Shalaby, M. Ashraf; Coxon, Bruce, Journal of the Chemical Society. Perkin transactions I, 1992, # 12, p. 1511 - 1518

  摘要：

  DOI：

文献信息

• Resonance-stabilized phenylazo-ene-phenylimine cations of cyclobutanetetraone derivatives
  作者：Hassan S El Khadem、Bruce Coxon

  DOI：10.1016/s0008-6215(02)00119-2

  日期：2002.11

  Cyclobutenedione phenylazo-phenylamines A,ere found to exhibit bathochromic shifts in acidic media and hypsochromic shifts in basic media, like phenylazo-phenylhydrazones. The bathochromic shifts are due to the formation of resonance-stabilized cations and the hypsochromic shifts to enolization. The phenylazo-phenylamines and their cations and anions have been studied by NMR spectroscopy. (C) 2002 Elsevier Science Ltd. All rights reserved.