(2-pyridylphenylketone)2Zn(CF3SO3)2 | 356041-62-8

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: (2-pyridylphenylketone)2Zn(CF3SO3)2
• CAS: 356041-62-8
• 化学式: C₂₆H₁₈F₆N₂O₈S₂Zn
• 分子量: 729.95
• InChiKey: HXJWSQJZIXSUEG-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2-苯甲酰吡啶 、 zinc trifluoromethanesulfonate 以 甲醇 为溶剂， 以72%的产率得到(2-pyridylphenylketone)2Zn(CF3SO3)2
  参考文献：
  名称：

  Chelate-stabilized zinc complexes of alcohols and carbonyl compounds: pyridylphenylketone and pyridylphenylmethanol

  摘要：

  The reactions of various zinc salts with the chelating ketone pyridylphenylketone (PPK) and the chelating alcohol pyridylphenylmethanol (PPM) were studied. 2:1 reactions of PPK with ZnX2 yielded octahedral complexes (PPK)(2)ZnX2 with X = OSO2CF3, Cl, Br, NCS. 1:1 reactions yielded the square pyramidal complexes [(PPK)(2)ZnHal](2)ZnHal(4) with X = Br, I and the trigonal-bipyramidal complex [(PPK)Zn(NCS)(2)](2). With Zn(SC6F2), the tetrahedral 1:I complex (PPK)(2)Zn(SC6F2), resulted. Methanol as a coligand was incorporated in the octahedral complex [(PPK)(2)Zn(CH3OH)(2)](BF4)(2). Of the PPM complexes, only (PPM)(2)Zn(OSO2CF3)(2) was analogous to the corresponding PPK complex. The zinc halides produced the octahedral complexes [(PPM)(3)Zn]ZnHal, with X = Cl, Br. Zn[N(SiMe3)(2)](2) and PPM yielded polymeric zinc pyridylphenylmethoxide. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0020-1693(01)00395-4