1,5-diethynyl-3-ethynyl-2,4,6-trimethylbenzene;platinum(2+);tributylphosphane;1,3,5-tris(ethynyl)-2,4,6-trimethylbenzene | 216143-20-3

• 分子结构分类: 有机化合物
• 英文名称: 1,5-diethynyl-3-ethynyl-2,4,6-trimethylbenzene;platinum(2+);tributylphosphane;1,3,5-tris(ethynyl)-2,4,6-trimethylbenzene
• CAS: 216143-20-3
• 化学式: C₁₃₂H₂₀₄P₆Pt₃
• 分子量: 2562.15
• InChiKey: IVDIBUZCPFNIBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  chloroplatinum(1+);tributylphosphane;1,3,5-tris(ethynyl)-2,4,6-trimethylbenzene 、 1,3,5-triethynylmesitylene 在 copper(l) chloride HNEt₂ 作用下， 以 二乙胺 为溶剂， 以70%的产率得到1,5-diethynyl-3-ethynyl-2,4,6-trimethylbenzene;platinum(2+);tributylphosphane;1,3,5-tris(ethynyl)-2,4,6-trimethylbenzene
  参考文献：
  名称：

  Synthesis of organometallic dendrimers with a backbone composed of platinum-acetylide units

  摘要：

  Novel organometallic dendrimers containing platinum-acetylide units in the main chain have been synthesized up to a henicosanuclear complex (12) using triethynylmesitylene (4) as a bridging ligand. The molecular structure of trinuclear complex (5b), which is a model core of the dendrimer, has been established by an X-ray analysis. (C) 1998 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(98)00788-8