N-{3,5-Bis-[3,5-bis-(4-bromo-benzyloxy)-benzyloxy]-benzyl}-4-diphenylphosphanyl-benzamide | 352212-71-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N-{3,5-Bis-[3,5-bis-(4-bromo-benzyloxy)-benzyloxy]-benzyl}-4-diphenylphosphanyl-benzamide
• CAS: 352212-71-6
• 化学式: C₆₈H₅₄Br₄NO₇P
• 分子量: 1347.77
• InChiKey: VRMGQBZRURQQBT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  16.9
• 重原子数：
  81.0
• 可旋转键数：
  24.0
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  84.48
• 氢给体数：
  1.0
• 氢受体数：
  7.0

反应信息

• 作为反应物：
  描述：

  、 N-{3,5-Bis-[3,5-bis-(4-bromo-benzyloxy)-benzyloxy]-benzyl}-4-diphenylphosphanyl-benzamide 、 silver tetrafluoroborate 在 MeCN 作用下， 以 二氯甲烷 、 水 为溶剂， 以99%的产率得到
  参考文献：
  名称：

  Chemistry on Surface-Confined Molecules:  An Approach to Anchor Isolated Functional Units to Surfaces

  摘要：

  The synthesis of surface-confined, nanometer-sized dendrimers and Au nanoparticles was performed starting from single Pd-II pincer adsorbate molecules (10) embedded as isolated species into 11-mercapto-1-undecanol and decanethiol self-assembled monolayers (SAMs) on gold. The coordination of monolayer-protected Au nanoclusters (MPCs) bearing phosphine moieties at the periphery (13), or dendritic wedges (8) having a phosphine group at the focal point, to SAMs containing individual Pd-II pincer molecules was monitored by tapping mode atomic force microscopy (TM AFM). The individual Pd-II pincer molecules embedded in the decanethiol SAM were visualized by their coordination to phosphine MPCs 13; isolated objects with a height of 3.5 +/- 0.7 nm were observed by TM AFM. Reaction of these embedded Pd-II pincer molecules with the dendritic wedge 8 yielded individual molecules with a height of 4.3 +/- 0.2 nm.

  DOI：

  10.1021/ja010257c
• 作为产物：
  描述：

  2-{3,5-Bis-[3,5-bis-(4-bromo-benzyloxy)-benzyloxy]-benzyl}-isoindole-1,3-dione 在 1-羟基苯并三唑 、 一水合肼 、 N,N'-二环己基碳二亚胺 作用下， 以 四氢呋喃 、 乙醇 、 氯仿 为溶剂， 反应 5.0h， 生成 N-{3,5-Bis-[3,5-bis-(4-bromo-benzyloxy)-benzyloxy]-benzyl}-4-diphenylphosphanyl-benzamide
  参考文献：
  名称：

  Chemistry on Surface-Confined Molecules:  An Approach to Anchor Isolated Functional Units to Surfaces

  摘要：

  The synthesis of surface-confined, nanometer-sized dendrimers and Au nanoparticles was performed starting from single Pd-II pincer adsorbate molecules (10) embedded as isolated species into 11-mercapto-1-undecanol and decanethiol self-assembled monolayers (SAMs) on gold. The coordination of monolayer-protected Au nanoclusters (MPCs) bearing phosphine moieties at the periphery (13), or dendritic wedges (8) having a phosphine group at the focal point, to SAMs containing individual Pd-II pincer molecules was monitored by tapping mode atomic force microscopy (TM AFM). The individual Pd-II pincer molecules embedded in the decanethiol SAM were visualized by their coordination to phosphine MPCs 13; isolated objects with a height of 3.5 +/- 0.7 nm were observed by TM AFM. Reaction of these embedded Pd-II pincer molecules with the dendritic wedge 8 yielded individual molecules with a height of 4.3 +/- 0.2 nm.

  DOI：

  10.1021/ja010257c