5-(2,6-dichloro-3-nitrophenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin | 131336-19-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 5-(2,6-dichloro-3-nitrophenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin
• 英文别名: meso-5-(2,6-dichloro-3-nitrophenyl)-10,15,20-tri(2,6-dichlorophenyl)porphyrin；5-(2,6-dichloro-3-nitrophenyl)-10,15,20-tri-(2,6-dichlorophenyl)porphyrin
• CAS: 131336-19-1
• 化学式: C₄₄H₂₁Cl₈N₅O₂
• 分子量: 935.307
• InChiKey: WWWGTMJNJUBJGH-HEQJDNLBSA-N

物化性质

• 密度：
  1.564±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  16.46
• 重原子数：
  59.0
• 可旋转键数：
  5.0
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  100.5
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为反应物：
  描述：

  5-(2,6-dichloro-3-nitrophenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin 在 盐酸 、 tin(ll) chloride 作用下， 反应 2.0h， 生成 5-(3-Amino-2,6-dichlorophenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin
  参考文献：
  名称：

  Dimeric Mn(III)-tetraarylporphyrins as catalysts for H2O2-promoted olefin epoxidation.

  摘要：

  The first example of dimeric Mn(III)-tetraarylporphyrins able to catalyze olefin epoxidation is reported. In the presence of one equivalent of lipophilic bidentate ligand 3 the efficiency of some of these catalysts is among the highest reported to now in 30% H2O2-promoted epoxidation (up to 1500 overall catalytic cycles). Slightly better results were obtained replacing 3 with two equivalents of N-hexylimidazole 10.

  DOI：

  10.1016/s0040-4020(01)85369-2
• 作为产物：
  描述：

  吡咯 、 2,6-二氯-3-硝基苯甲醛 、 2,6-二氯苯甲醛 在 三氟化硼乙醚 、 2,3-二氯-5,6-二氰基-1,4-苯醌 作用下， 生成 meso-tetrakis-(2,6-dichlorophenyl)porphyrin 、 5-(2,6-dichloro-3-nitrophenyl)-10,15,20-tris(2,6-dichlorophenyl)porphyrin
  参考文献：
  名称：

  Dimeric Mn(III)-tetraarylporphyrins as catalysts for H2O2-promoted olefin epoxidation.

  摘要：

  The first example of dimeric Mn(III)-tetraarylporphyrins able to catalyze olefin epoxidation is reported. In the presence of one equivalent of lipophilic bidentate ligand 3 the efficiency of some of these catalysts is among the highest reported to now in 30% H2O2-promoted epoxidation (up to 1500 overall catalytic cycles). Slightly better results were obtained replacing 3 with two equivalents of N-hexylimidazole 10.

  DOI：

  10.1016/s0040-4020(01)85369-2

文献信息

• Banfi, Stefano; Montanari, Fernando; Quici, Silvio, Gazzetta Chimica Italiana, 1990, vol. 120, p. 435 - 442
  作者：Banfi, Stefano、Montanari, Fernando、Quici, Silvio

  DOI：——

  日期：——
• Banfi, Stefano; Montanari, Fernando; Quici, Silvio, Gazzetta Chimica Italiana, 1990, vol. 120, # 7, p. 435 - 441
  作者：Banfi, Stefano、Montanari, Fernando、Quici, Silvio

  DOI：——

  日期：——