Phenyl-pentafluorphenyl-dibromsilan | 173920-24-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenyl-pentafluorphenyl-dibromsilan
• 英文别名: dibromo-(2,3,4,5,6-pentafluorophenyl)-phenylsilane
• CAS: 173920-24-6
• 化学式: C₁₂H₅Br₂F₅Si
• 分子量: 432.057
• InChiKey: XWJUDACKNZEWSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.73
• 重原子数：
  20.0
• 可旋转键数：
  2.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  Phenyl-pentafluorphenyl-dibromsilan 在 双(三甲基硫化硅) 作用下， 反应 12.0h， 以100%的产率得到1,3-Diphenyl-1,3-bis(pentafluorphenyl)-cyclo-di(silthian)
  参考文献：
  名称：

  Synthese und Eigenschaften von 1,1,3,3-Tetrakis(pentafluorphenyl)-cyclo-di(silthian) und verwandten Verbindungen

  摘要：

  The synthesis of tetrakis(pentafluorophenyl)-cyclo-di(silthiane) and related compounds by reacting organosubstituted silanes with sulfur or hexamethyldisilthiane is reported The compounds are characterized by analysis, by relative molecular mass, by H-1, C-13, F-19, and Si-29 NMR spectroscopy, and by mass and IR spectra, respectively. Two Si-29 NMR signals of different intensity found for compounds with two different organic substituents on silicon are explained by the existence of diastereomers.

  DOI：

  10.1007/bf00824294
• 作为产物：
  描述：

  氯苯基硅烷 在 N-溴代丁二酰亚胺(NBS) 、 magnesium 作用下， 以 环己烷 为溶剂， 反应 36.0h， 生成 Phenyl-pentafluorphenyl-dibromsilan
  参考文献：
  名称：

  Synthese und Eigenschaften von 1,1,3,3-Tetrakis(pentafluorphenyl)-cyclo-di(silthian) und verwandten Verbindungen

  摘要：

  The synthesis of tetrakis(pentafluorophenyl)-cyclo-di(silthiane) and related compounds by reacting organosubstituted silanes with sulfur or hexamethyldisilthiane is reported The compounds are characterized by analysis, by relative molecular mass, by H-1, C-13, F-19, and Si-29 NMR spectroscopy, and by mass and IR spectra, respectively. Two Si-29 NMR signals of different intensity found for compounds with two different organic substituents on silicon are explained by the existence of diastereomers.

  DOI：

  10.1007/bf00824294