sodium 5-norbornene-2-carboxyate | 66787-51-7

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: sodium 5-norbornene-2-carboxyate
• 英文别名: sodium;(1R,2R,4R)-bicyclo[2.2.1]hept-5-ene-2-carboxylate
• CAS: 66787-51-7
• 化学式: C₈H₉O₂*Na
• 分子量: 160.148
• InChiKey: TUHMYUUOWAYQBK-FNCXLRSCSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.05
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.62
• 拓扑面积：
  40.1
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  sodium 5-norbornene-2-carboxyate 在 盐酸 作用下， 生成
  参考文献：
  名称：

  Synthesis and structure proof of C-2 and C-4 monofunctionalized brexanes and brendanes

  摘要：

  DOI：

  10.1021/jo00414a025

文献信息

• The intercalation of bicyclic and tricyclic carboxylates into layered double hydroxides
  作者：Aamir I. Khan、Gareth R. Williams、Gang Hu、Nicholas H. Rees、Dermot O'Hare

  DOI：10.1016/j.jssc.2010.09.036

  日期：2010.12

  Twenty-four nanocomposites built from layered double hydroxides and bicyclic and tricyclic carboxylates have been synthesised for the first time. Eight carboxylates were successfully intercalated into [LiAl(2)(OH)(6)]Cl center dot yH(2)O, [Ca(2)Al(OH)(6)]NO(3)center dot yH(2)O, and [Mg(2)Al(OH)(6)]NO(3)center dot yH(2)O, and the products fully characterised. Guest species incorporated include 1-adamantane carboxylate (1-AC) and 5-norbornene-2-endo-3-exo-dicarboxylate. In some cases, carbonate anions were co-intercalated with the organic guest, and in others poorly crystalline aluminium hydroxides formed as by-products. Sharper resonances were observed in the (13)C solid-state NMR spectra of the 1-AC intercalates than in the spectrum of pure 1-AC, suggesting increased order in the arrangement of the cyclic cages in the intercalates. Where possible, time-resolved in situ X-ray diffraction was employed to study the nanoscopic steps involved in the intercalation reactions. These investigations showed that the reactions are one-step processes, proceeding directly to the fully exchanged intercalate with no intermediate phases. The intercalation processes were found to be nucleation controlled. (C) 2010 Elsevier Inc. All rights reserved.
• NICKON A.; KWASNIK H. R.; MATHEW C. T.; SWARTZ T. D.; WILLIAMS R. O.; DIG+, J. ORG. CHEM., 1978, 43, NO 20, 3904-3916
  作者：NICKON A.、 KWASNIK H. R.、 MATHEW C. T.、 SWARTZ T. D.、 WILLIAMS R. O.、 DIG+

  DOI：——

  日期：——