| 156975-49-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• CAS: 156975-49-4
• 化学式: C₁₃H₁₂HgO₃
• 分子量: 416.826
• InChiKey: WCCCHNBPDHOCEY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  在 air 作用下， 以 neat (no solvent) 为溶剂， 生成 mercury(II) oxide
  参考文献：
  名称：

  Thermal investigations on arylmercury(II) complexes of kojic acid and maltol

  摘要：

  Arylmercury(ll) derivatives of kojic acid and maltol of the type pXC(6)H(4)HgL(1) (I) and p-XC(6)H(4)HgL(2) (II) [HL(1)=kojic acid, HL(2)=maltol; X=M, MO, NO2] have been synthesised. IR spectral studies indicate that both the ligands act as bidentate groups, bonding to the mercury(II) ion through phenolic and carbonyl oxygens. From TG curves, the order and activation energy of the thermal decomposition reaction have been elucidated. The variation of the activation energy has been correlated with the nature of the substituents on the phenyl ring. The heat of reaction has been elucidated from differential scanning calorimetric studies. The fragmentation pattern has been analysed on the basis of mass spectre.[GRAPHICS]P>-1.

  DOI：

  10.1007/bf01979250
• 作为产物：
  描述：

  麦芽醇 、 对甲苯基氯化汞 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Thermal investigations on arylmercury(II) complexes of kojic acid and maltol

  摘要：

  Arylmercury(ll) derivatives of kojic acid and maltol of the type pXC(6)H(4)HgL(1) (I) and p-XC(6)H(4)HgL(2) (II) [HL(1)=kojic acid, HL(2)=maltol; X=M, MO, NO2] have been synthesised. IR spectral studies indicate that both the ligands act as bidentate groups, bonding to the mercury(II) ion through phenolic and carbonyl oxygens. From TG curves, the order and activation energy of the thermal decomposition reaction have been elucidated. The variation of the activation energy has been correlated with the nature of the substituents on the phenyl ring. The heat of reaction has been elucidated from differential scanning calorimetric studies. The fragmentation pattern has been analysed on the basis of mass spectre.[GRAPHICS]P>-1.

  DOI：

  10.1007/bf01979250