N,N'-bis[(2-(2,6-diisopropylphenylamino)benzylidene)]-1,2-ethanediamine | 1043886-58-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: N,N'-bis[(2-(2,6-diisopropylphenylamino)benzylidene)]-1,2-ethanediamine
• 英文别名: (o-C6H4(NH-2,6-iPr2C6H3)-CH=N)2CH2CH2；N-[2-[2-[[2-[2,6-di(propan-2-yl)anilino]phenyl]methylideneamino]ethyliminomethyl]phenyl]-2,6-di(propan-2-yl)aniline
• CAS: 1043886-58-3
• 化学式: C₄₀H₅₀N₄
• 分子量: 586.864
• InChiKey: KFZBBVWPQSXJCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.4
• 重原子数：
  44
• 可旋转键数：
  13
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.35
• 拓扑面积：
  48.8
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N'-bis[(2-(2,6-diisopropylphenylamino)benzylidene)]-1,2-ethanediamine 、 三甲基铝 以 甲苯 为溶剂， 以62%的产率得到[AlMe2(N,N'-bis[2-(2,6-diisopropylphenylamino)benzylidene]-1,2-ethanediamine)]
  参考文献：
  名称：

  Anilido-aldimine aluminum complexes: Synthesis, characterization and lactide polymerization

  摘要：

  The synthesis of six bimetallic dimethyl aluminum anilido-aldimine complexes, active for the ring opening polymerization of rac-lactide, is reported. An efficient synthetic route to these ligands utilizing isolated lithium amide salts allows for the synthesis of novel cyclohexylamide-substituted ligands, as well as improving the yields of diisopropylphenylamino-substituted ligands, with both ethyl and propyl backbones. Less sterically encumbered methylamide-substituted ligands were prepared through the condensation of ortho-methylaminobenzaldehyde with the appropriate diamine. A monometallic intermediate species, L(AlMe2), was isolated and crystallographically characterized, illustrating the preference these ligands display for bis(bidentate) coordination. L(AlMe2)(2) complexes 8-13 are efficient mediators of the ring opening polymerization of rac-lactide, with solution polymerizations displaying first-order rate constants, molecular weights very close to the theoretical values and polydispersity indexes as low as 1.07. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.02.003
• 作为产物：
  描述：

  N,N'-(ethane-1,2-diyl)bis(1-(2-fluorophenyl)methanimine) 、 2,6-二异丙基苯胺 在 正丁基锂 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 24.0h， 以75%的产率得到N,N'-bis[(2-(2,6-diisopropylphenylamino)benzylidene)]-1,2-ethanediamine
  参考文献：
  名称：

  Anilido-aldimine aluminum complexes: Synthesis, characterization and lactide polymerization

  摘要：

  The synthesis of six bimetallic dimethyl aluminum anilido-aldimine complexes, active for the ring opening polymerization of rac-lactide, is reported. An efficient synthetic route to these ligands utilizing isolated lithium amide salts allows for the synthesis of novel cyclohexylamide-substituted ligands, as well as improving the yields of diisopropylphenylamino-substituted ligands, with both ethyl and propyl backbones. Less sterically encumbered methylamide-substituted ligands were prepared through the condensation of ortho-methylaminobenzaldehyde with the appropriate diamine. A monometallic intermediate species, L(AlMe2), was isolated and crystallographically characterized, illustrating the preference these ligands display for bis(bidentate) coordination. L(AlMe2)(2) complexes 8-13 are efficient mediators of the ring opening polymerization of rac-lactide, with solution polymerizations displaying first-order rate constants, molecular weights very close to the theoretical values and polydispersity indexes as low as 1.07. (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.02.003

文献信息

• 双核胺亚胺镁配合物及其制备方法和应用
  申请人：济南大学

  公开号：CN109651409A

  公开（公告）日：2019-04-19

  本发明公开了一种双核胺亚胺镁配合物及其制备方法和应用，其具有式Ⅰ所述的结构式，其中，R为氢、甲基、乙基或异丙基。本发明双核胺亚胺催化剂由配体和Mg(nBu)2和苄醇一锅法反应而得，制备方法简单，成本低，产品收率高，该化合物结构变化多样，金属中心镁与配体的N，N原子配位，可作为环内酯开环聚合反应的催化剂，催化活性高、立体选择性好、不需要助催化剂、反应速率快，聚合反应操作简单，得到的聚合产物分子量分布窄、分子量可控、产率高，可以广泛用于环内酯开环聚合，是一种十分理想的催化剂。
• Bimetallic anilido-aldimine Al or Zn complexes for efficient ring-opening polymerization of ε-caprolactone
  作者：Wei Yao、Ying Mu、Aihong Gao、Wei Gao、Ling Ye

  DOI：10.1039/b719017d

  日期：——

  Four bimetallic Al or Zn complexes supported by anilido-aldimine ligands (o-C6H4(NHAr)–CHN)2CH2CH2 (Ar = 2,6-Me2C6H3, L11H2; Ar = 2,6-iPr2C6H3, L22H2) have been synthesized and characterized. Treatment of L11H2 or L22H2 with two equiv. of AlMe3 gives bimetallic complex L11(AlMe2)21 or L22(AlMe2)22, respectively. Reaction of L11H2 or L22H2 with two equiv. of ZnEt2 leads to bimetallic complex L11(ZnEt)23 or L22(ZnEt)24, respectively. All of the complexes 1–4 are efficient catalysts for ring-opening polymerization of ε-caprolactone (CL) in the presence of benzyl alcohol and catalyze the polymerization of CL in living fashion yielding polymers with a narrow polydispersity index. The activity of bimetallic Zn complexes 3 and 4 is higher than bimetallic Al complexes 1 and 2.

  合成了四种由苯胺基醛亚胺配体 (o-C6H4(NHAr)→CHN)2CH2CH2 (Ar = 2,6-Me2C6H3, L11H2; Ar = 2,6-iPr2C6H3, L22H2) 支持的双金属 Al 或 Zn 配合物特点。用两当量治疗 L11H2 或 L22H2。 AlMe3 分别得到双金属络合物 L11(AlMe2)21 或 L22(AlMe2)22。 L11H2 或 L22H2 与两个当量的反应。 ZnEt2 分别形成双金属络合物 L11(ZnEt)23 或 L22(ZnEt)24。所有配合物 1–4 都是在苯甲醇存在下进行 ε-己内酯 (CL) 开环聚合的有效催化剂，并以活泼的方式催化 CL 的聚合，产生具有窄多分散指数的聚合物。双金属Zn配合物3和4的活性高于双金属Al配合物1和2。