iodo(pyridine-N)(5,10,15,20-tetraphenylporphyrinato-κ4N)rhodium(III) toluene solvate | 335342-71-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: iodo(pyridine-N)(5,10,15,20-tetraphenylporphyrinato-κ4N)rhodium(III) toluene solvate
• CAS: 335342-71-7
• 化学式: C₇H₈*C₄₉H₃₃IN₅Rh
• 分子量: 1013.79
• InChiKey: VLNYFFYDUVUKKE-GVHKZQBISA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶 、 iodo(5,10,15,20-tetraphenylporphyrinato-κ4N)rhodium(III) 、 甲苯 以 正戊烷 为溶剂， 生成 iodo(pyridine-N)(5,10,15,20-tetraphenylporphyrinato-κ4N)rhodium(III) toluene solvate
  参考文献：
  名称：

  Superimposed saddle and ruffled distortions of the porphyrin in iodo(pyridine-N)(5,10,15,20-tetraphenylporphyrinato-κ⁴N)rhodium(III) toluene solvate

  摘要：

  In the title compound, [RhI(C44H28N4)(C5H5N)].C7H8, the porphyrin ring experiences significant distortion from planarity (a saddle conformation with a superimposed ruffling), as a result of steric interactions with the 2,6-H atoms of the axial pyridine ligand. This also leads to a slight lengthening of the Rh-pyridine bond [Rh-N 2.102 (7) Angstrom] relative to those seen in other pyridine adducts of six-coordinate Rh-III. The metric parameters of the porphyrin core are comparable with those of related metalloporphyrin derivatives. No significant intermolecular interactions are observed between the metalloporphyrin and disordered solvate species.

  DOI：

  10.1107/s0108270101001536