3-甲基丁基巯基乙酸酯 | 16849-97-1

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 中文名称: 3-甲基丁基巯基乙酸酯
• 英文名称: Mercapto-essigsaeure-isopentylester
• 英文别名: Isopentyl thioglycolate；3-methylbutyl 2-sulfanylacetate
• CAS: 16849-97-1
• 化学式: C₇H₁₄O₂S
• 分子量: 162.253
• InChiKey: WNMCXBGTMQTKEU-UHFFFAOYSA-N

物化性质

• 沸点：
  213.7±13.0 °C(Predicted)
• 密度：
  1.001±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  10
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  27.3
• 氢给体数：
  1
• 氢受体数：
  3

安全信息

• 海关编码：
  2930909090

文献信息

• Process for producing 3-phenyluracil compounds
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1101761A2

  公开（公告）日：2001-05-23

  The uracil compounds represented by the formula [V]: wherein R1 represents C1-C5 perfluoroalkyl group and Q represents an aromatic group, can be produced by making the amide compounds represented by the formula [II]: wherein R1 and Q have the same meanings defined above, or its hydrate react with a cyanate salt in the presence of a protonic acid.

  由式[V]代表的尿嘧啶化合物：其中 R1 代表 C1-C5 全氟烷基，Q 代表芳香基团，可通过制造由式[II]代表的酰胺化合物（其中 R1 和 Q 具有与上述定义相同的含义）或其水合物，在质子酸存在下与氰酸盐反应制得。
• Method for producing polymer
  申请人：National University Corporation Hokkaido University

  公开号：EP2060594A2

  公开（公告）日：2009-05-20

  Problem to be solved: To provide a method for producing a polymer having a desired composition in a high-yield, immediate and easy manner by continuously producing and reproducing acetyl-CoA without using a purified enzyme or expensive ATP. Solution: A method for producing a polymer includes a chemical thioester exchange reaction for forming an acetyl-CoA by reacting an acetyl-thioester with CoA, a monomer-producing reaction for forming a (monomer precursor)-CoA derivative by reacting at least one monomer precursor compound with the acetyl-CoA and a polymerization reaction for forming the polymer compriseing units of the monomer by polymerizing the (monomer precursor)-CoA derivative.

  有待解决的问题提供一种不使用纯化酶或昂贵的 ATP，通过连续生产和复制乙酰-CoA，高产、快速、简便地生产具有所需成分的聚合物的方法。 解决方案一种生产聚合物的方法包括：通过乙酰硫酯与 CoA 反应形成乙酰-CoA 的硫酯交换化学反应；通过至少一种单体前体化合物与乙酰-CoA 反应形成（单体前体）-CoA 衍生物的单体生成反应；以及通过聚合（单体前体）-CoA 衍生物形成由单体单元组成的聚合物的聚合反应。
• 6-Hydroxy-5,6-dihydrouracils as herbicides
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1095935B1

  公开（公告）日：2008-12-17
• METHOD OF FORMING A GRAFT POLYOL AND POLYURETHANE ARTICLE FORMED FROM THE GRAFT POLYOL
  申请人：BASF SE

  公开号：EP2066720A1

  公开（公告）日：2009-06-10
• TRIESTERS FROM ALPHA-AND-BETA-HYDROXYESTERS
  申请人：Bradshaw John D.

  公开号：US20160145189A1

  公开（公告）日：2016-05-26

  A method of making a benzyl cis-cyclohexane 1,2-dicarboxylate triester having the steps: a. forming a reaction mixture by reacting the following three components: i. a synthetic or biobased reagent selected from the group consisting of an alpha-hydroxyester and a beta-hydroxyester, ii. an anhydride selected from the group consisting of cis-hexahydrophthalic anhydride, 4-methylcyclohexane-1,2-dicarboxylic anhydride, and 3-methylcyclohexane-1,2-dicarboxylic anhydride, and iii. an alkylamine catalyst; and b. contacting benzyl chloride with the reaction mixture to yield a product that is free of phthalates and includes at least one benzyl cis-cyclohexane 1,2-dicarboxylate triester.