9-tricyclo[3.3.1.1^3,7]decylidene-9,10-dihydroanthracene | 192184-78-4

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 9-tricyclo[3.3.1.1^3,7]decylidene-9,10-dihydroanthracene
• 英文别名: 9-(9,10-dihydroanthrylidene)adamantane；10-(2-adamantylidene)-9H-anthracene
• CAS: 192184-78-4
• 化学式: C₂₄H₂₄
• 分子量: 312.455
• InChiKey: ZFYHWSOGOFVUGG-UHFFFAOYSA-N

物化性质

• 沸点：
  462.1±25.0 °C(Predicted)
• 密度：
  1.163±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  24
• 可旋转键数：
  0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  9-tricyclo[3.3.1.1^3,7]decylidene-9,10-dihydroanthracene 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 以99%的产率得到9,10-dihydrospiro[anthracene-9,2'-oxirane-3',2''-tricyclo-[3.3.1.1^3,7]decane]
  参考文献：
  名称：

  Oxiranes having an acridane structure as a novel chemiluminescent precursor: synthesis and chemiluminescent studies

  摘要：

  Oxirane derivatives having acridane and adamantane structures were designed as a novel chemiluminescent precursor and were found to have a characteristic chemiluminescent ability which is introduced by a two-step trigger reaction involving treatment with alkaline H2O2 and subsequent acidic treatment. Structural study of the oxirane derivatives showed that the CIEEL mechanism is involved in this chemiluminescent reaction and it was also found that the chemiluminescent profile is affected by the kind of acid employed in the trigger reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(01)00216-2
• 作为产物：
  描述：

  2-(9,10-Dihydro-anthracen-9-yl)-adamantan-2-ol 在 对甲苯磺酸 作用下， 生成 9-tricyclo[3.3.1.1^3,7]decylidene-9,10-dihydroanthracene
  参考文献：
  名称：

  A novel chemiluminescence from the reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridines and peroxyacid

  摘要：

  Reaction of 9-arylmethylene-10-methyl-9,10-dihydroacridine (1) with more than two equivalents of m-choloroperoxybenzoic acid in CH2Cl2 affords intermediary beta-hydroxy-tertiary-alkyl peroxyester (5) decomposing to N-methylacridone and aromatic aldehyde with chemiluminescence by a CIEEL mechanism.

  DOI：

  10.1016/s0040-4039(00)73237-0

文献信息

• 9-Adamantylidene-10-alkyl-9,10-dihydroacridine oxide as a novel and potential chemiluminescent precursor: Proximity effect of the nitrogen atom
  作者：Takeshi Imanishi、Yohko Ueda、Masatoshi Minagawa、Nobuhiro Hoshino、Kazuyuki Miyashita

  DOI：10.1016/s0040-4039(97)00791-0

  日期：1997.6

  An oxirane derivative having acridane and adamantane moieties was prepared and proved to show potential chemiluminescent property on treatment with alkaline hydroperoxide and subsequently with hydrochloric acid, in which the electron-donating property of the nitrogen was experimentally shown to play an important role for the chemiluminescence. (C) 1997 Elsevier Science Ltd.