catena-poly[[(pyridin-4-ol-κN)silver(I)]-μ-pyridin-4-olato-κ2N:O] | 849487-70-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: catena-poly[[(pyridin-4-ol-κN)silver(I)]-μ-pyridin-4-olato-κ2N:O]
• CAS: 849487-70-3
• 化学式: C₁₀H₉AgN₂O₂
• 分子量: 297.062
• InChiKey: FUAFKBBDYLGJKO-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  4-羟基吡啶 、 silver nitrate 以 乙醇 为溶剂， 生成 catena-poly[[(pyridin-4-ol-κN)silver(I)]-μ-pyridin-4-olato-κ2N:O]
  参考文献：
  名称：

  catena-Poly[[(pyridin-4-ol-κN)silver(I)]-μ-pyridin-4-olato-κ²N:O]

  摘要：

  The title complex, [Ag(C5H4NO)(C5H5NO)](n), consists of a polymeric neutral chain involving both a neutral pyridin-4-ol ligand and a deprotonated pyridin-4-olate monoanion. The Ag-I atom shows a T-shaped coordination geometry, defined by one N atom of the pyridin-4-ol and one O and one N atom of two independent pyridin-4-olate bridges; the N - Ag - N moiety is approximately linear. The polymeric chains are connected via strong O - H ... O hydrogen bonds and offset pi-pi interactions into a three-dimensional network.

  DOI：

  10.1107/s0108270104026757