| 54936-96-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• CAS: 54936-96-8
• 化学式: C₁₄H₁₆Cl₂CuN₄O₂
• 分子量: 406.759
• InChiKey: UCOCOCVCEBTYIC-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-乙酰氨基吡啶 、 copper dichloride 以 further solvent(s) 为溶剂， 生成
  参考文献：
  名称：

  Hahn, F. L.; Wolf, H., Zeitschrift fur anorganische Chemie, 1925, vol. 144, p. 117 - 127

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B1, 142, page 309 - 311
  作者：

  DOI：——

  日期：——
• Transition metal complexes of N-substituted derivatives of 2-[(N-acetyl) amino]pyridine
  作者：J. Bould、B.J. Brisdon

  DOI：10.1016/s0020-1693(00)91089-2

  日期：1976.1
• Synthesis, X-ray crystal structures, spectroscopic properties and magnetism of copper(II) compounds of formula trans-Cu(LL)2(anion)2, with N-(pyridin-2-yl)acetamide and N-(pyrimidin-2-yl)acetamide as ligands: Unexpected absence of hydrogen bonding to the non-coordinating nitrogen atom of the ligand
  作者：Gerard A. van Albada、Isja Dominicus、Ilpo Mutikainen、Urho Turpeinen、Jan Reedijk

  DOI：10.1016/j.poly.2007.04.035

  日期：2007.8

  A coordination chemistry and lattice engineering study of 10 new Cu(II) compounds with the ligands N-(pyridin-2-yl)acetamide (Haap) and N-(pyrimidin-2-yl)acetamide (Haapm) with the general formula Cu(LL)(2)(anion)(2) is described. The bidentate ligands bind in a N,O-chelating mode and the used anions are ClO4-, CF3SO3-, BF4-, NO3-, Cl-. For five of the compounds a 3D crystal and molecular structure analysis has been performed. All Cu(II) ions have a tetragonal-based geometry; the basal plane of each copper consists of a N and an O atom of two different bischelating N,O-donor ligands; Cu-N distances vary from 2.00 to 2.04 angstrom and Cu-O distances are between 1.93 and 1.96 angstrom, whereas the apical sites are occupied by an atom of the anions, thereby providing an elongated octahedral geometry (Cu-anion contacts are between 2.41 and 2.81 angstrom).The intermolecular interactions are all involving multiple H-bond systems, providing a 2D polymeric array for most of the compounds. The chloride compound forms a zigzag polymeric array of hydrogen bonds. Most surprisingly, the lion-coordinating pyrimidine nitrogen atom, does not take part in any lattice hydrogen bonding. (c) 2007 Elsevier Ltd. All rights reserved.