[Fe(tris(6-neopentylamino-2-pyridylmethyl)amine)(OMe)2]ClO4 | 213131-11-4

• 分子结构分类: 有机化合物
• 英文名称: [Fe(tris(6-neopentylamino-2-pyridylmethyl)amine)(OMe)2]ClO4
• CAS: 213131-11-4
• 化学式: C₃₅H₅₇FeN₇O₂*ClO₄
• 分子量: 763.181
• InChiKey: BMLOVJHDPRNHLS-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 iron perchlorate hexahydrate 、 tris[(6-neopentylamino-2-pyridyl)methyl]amine 以 甲醇 为溶剂， 以65%的产率得到[Fe(tris(6-neopentylamino-2-pyridylmethyl)amine)(OMe)2]ClO4
  参考文献：
  名称：

  Synthesis, Structure, and Spectroscopic Properties of [Feiii(tnpa)(OH)(PhCOO)]ClO4: A Model Complex for an Active Form of Soybean Lipoxygenase-1

  摘要：

  The cis configuration between the hydroxo and the carboxylato and the three amino groups of the tetradentate, tripodal ligand tris(6-neopentylamino-2-pyridylmethyl)amine favors the formation of hydrogen bonds which stabilize the hydroxo-Feiii complex 1. Thus, its structure closely resembles that of the active center of Feiii -soybean lipoxygenase-1, which also contains a six-coordinate Feiii atom.

  DOI：

  10.1002/(sici)1521-3773(19980817)37:15<2102::aid-anie2102>3.0.co;2-a