6-amino-5-formyl-1,3-dimethyluracil-benzoylhydrazone | 220529-20-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 6-amino-5-formyl-1,3-dimethyluracil-benzoylhydrazone
• 英文别名: N-[(4-amino-1,3-dimethyl-2,6-dioxopyrimidin-5-yl)methylideneamino]benzamide
• CAS: 220529-20-4
• 化学式: C₁₄H₁₅N₅O₃
• 分子量: 301.305
• InChiKey: MTOQQGCOZOSMFV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  108
• 氢给体数：
  2
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  6-amino-5-formyl-1,3-dimethyluracil-benzoylhydrazone 、 copper(II) nitrate trihydrate 以 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Synthesis, spectral and XRD studies on three O-nitrito-complexes with new N,N,O-tridentate Schiff bases derived from 6-amino-5-formyl-1,3-dimethyluracil and semicarbazide, acetylhydrazine and benzoylhydrazine

  摘要：

  DOI：

  10.1016/s0277-5387(98)00303-9

文献信息

• Ni(II) and Cu(II) complexes with the dianionic N,N,O-tridentate Schiff base 6-amino-5-formyl-1,3-dimethyluracil-benzoylhydrazone
  作者：Francisco Hueso-Ureña、Nuria A. Illán-Cabeza、Miguel N. Moreno-Carretero、Antonio L. Peñas-Chamorro、René Faure

  DOI：10.1016/s0277-5387(00)00309-0

  日期：2000.3

  From the reaction between Cu(II) and Ni(II) salts and the Schiff base 6-amino-5-formyl-1,3-dimethyluracil-benzo (H(2)BEZDO), in dimethylformamide (DMF)-water and ammonia media, the complexes Ni(BEZDO) . H2O . NH3, Cu(BEZDO) . H2O . NH3 and [Cu(BEZDO)(H2O)] . H2O containing the dianionic organic ligand have been obtained. These compounds have been studied by IR, electronic and EPR spectroscopy and magnetic measurements. The structure of [Cu(BEZDO) (H2O)] . H2O has been solved by means of X-ray diffraction methods. The coordination environment around the Cu(II) may be described as a square-plane structure in which the Schiff base acts as tridentate ligand through the N(6), N(51) and O(52) atoms, making two five- and six-membered chelate rings. The coordination sphere is completed with the oxygen atom of a water molecule; any additional interactions with potential donor atoms in the axial direction have not been found. The crystal structure is formed by infinite hydrogen-bonded monodimensional chains, in which the nearest metal centres are at distances of 4.511 and 3.585 Angstrom. (C) 2000 Elsevier Science Ltd All rights reserved.