2,7-bis(5-octylthiophen-2-yl)-9H-fluoren-9-one | 1021189-20-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 2,7-bis(5-octylthiophen-2-yl)-9H-fluoren-9-one
• 英文别名: 2,7-bis(5-octylthien-2-yl)fluoren-9-one；2,7-Bis(5-octylthiophen-2-yl)fluoren-9-one
• CAS: 1021189-20-7
• 化学式: C₃₇H₄₄OS₂
• 分子量: 568.888
• InChiKey: CTXGQLWGQHRXCE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  13.5
• 重原子数：
  40
• 可旋转键数：
  16
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  73.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,7-bis(5-octylthiophen-2-yl)-9H-fluoren-9-one 、 丙二腈 以 二甲基亚砜 为溶剂， 反应 12.0h， 以59.9%的产率得到2-(2,7-bis(5-octylthiophen-2-yl)-9H-fluoren-9-ylidene)malononitrile
  参考文献：
  名称：

  Synthesis and characterization of fluorene derivatives as organic semiconductors for organic field-effect transistor

  摘要：

  We have synthesized and characterized fluorene derivatives with alkylated thiophene as solution-processed organic semiconductors for organic field-effect transistor. HOMO/LUMO energy levels of the developed materials were tuned via different electron-acceptors. Organic field-effect transistor fabricated from dicyanovinylene-functionalized fluorine derivative with octyl thiophene as the side group exhibited n-channel characteristic with electron mobility of 0.0055 cm(2)/Vs and current on/off ratio similar to 10(6). Film surface morphology and texture were correlated with the corresponding device performance.

  DOI：

  10.1080/15421406.2019.1680014
• 作为产物：
  描述：

  2,7-二碘-9H-芴-9-酮 、 tributyl(5-octylthiophen-2-yl)stannane 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以95.1%的产率得到2,7-bis(5-octylthiophen-2-yl)-9H-fluoren-9-one
  参考文献：
  名称：

  Synthesis and characterization of fluorene derivatives as organic semiconductors for organic field-effect transistor

  摘要：

  We have synthesized and characterized fluorene derivatives with alkylated thiophene as solution-processed organic semiconductors for organic field-effect transistor. HOMO/LUMO energy levels of the developed materials were tuned via different electron-acceptors. Organic field-effect transistor fabricated from dicyanovinylene-functionalized fluorine derivative with octyl thiophene as the side group exhibited n-channel characteristic with electron mobility of 0.0055 cm(2)/Vs and current on/off ratio similar to 10(6). Film surface morphology and texture were correlated with the corresponding device performance.

  DOI：

  10.1080/15421406.2019.1680014

文献信息

• Influence of polymorphism on charge transport properties in isomers of fluorenone-based liquid crystalline semiconductors
  作者：Frédéric Lincker、André-Jean Attias、Fabrice Mathevet、Benoît Heinrich、Bertrand Donnio、Jean-Louis Fave、Patrice Rannou、Renaud Demadrille

  DOI：10.1039/c2cc17276c

  日期：——

  We measured the charge carrier mobilities for two isomers of fluorenone-based liquid crystalline organic semiconductors from their isotropic down to crystalline states through one or two mesophases. Improved charge transport properties of melt-processed crystalline films were obtained for the isomer exhibiting a highly ordered mesophase below its disordered smectic phase.

  我们测量了芴酮基液晶有机半导体的两个异构体从其各向同性到通过一个或两个中间相到结晶态的电荷载流子迁移率。对于在其无序近晶相之下显示出高度有序的中间相的异构体，获得了熔融加工的结晶膜的改进的电荷传输性质。