[Ni(1,3-diaminopropane)2(H2O)2][TeO3]*H2O | 797756-77-5

• 分子结构分类: 有机化合物 - 有机杂环化合物
• 英文名称: [Ni(1,3-diaminopropane)2(H2O)2][TeO3]*H2O
• CAS: 797756-77-5
• 化学式: C₆H₂₄N₄NiO₂*H₂O*O₃Te
• 分子量: 436.586
• InChiKey: FRBVMGIKWARHLM-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  nickel(II) tellurite dihydrate 、 1,3-丙二胺 以 水 为溶剂， 以50%的产率得到[Ni(1,3-diaminopropane)2(H2O)2][TeO3]*H2O
  参考文献：
  名称：

  Chemical and Structural Studies of Some Transition Metal Tellurite Complexes with 1,3‐Diaminopropane

  摘要：

  Complexes of some Co(II), Ni(II), and Cu(II) tellurites with 1,3-diamino-propane ligand have been prepared and charaterized on the basis of elemental analyses, conductivity, magnetic moments, and spectral studies. These complexes have the general formula [MLn(H2O)(x)] TeO3 . yH(2)O, where M(II) = Co(II), Ni(II), and Cu(II); L = 1,3-diamino-propane; n = 3 [for Co(II)] and 2 [for Ni(II) and Cu(II)]; x = 0 [for Co(II) and Cu(II)] and 2 [for Ni(II)]; y = 4, 1 or 6 [for Co(II), Ni(II), and Cu(II) complexes, respectively]. TGA studies have also been carried out to study the patterns of their decomposition. The lattice constants and other cell parameters of the cobalt(II), nickel(II), and copper(II) tellurite complexes have been determined with the help of x-ray powder diffraction data. The Co(II) and Ni(II) complexes have an orthorhombic unit cell, whereas the Cu(II) complex has a tetragonal unit cell. On the basis of the cell parameters and diffraction data it has been concluded that the Co(II), Ni(II), and Cu(II) complexes have good crystallinity and packing efficiency.

  DOI：

  10.1081/sim-120039260