carbanide;4-methylbenzenethiolate;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;platinum(4+) | 208454-98-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: carbanide;4-methylbenzenethiolate;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;platinum(4+)
• CAS: 208454-98-2
• 化学式: C₁₉H₂₈PtS
• 分子量: 483.577
• InChiKey: BNGBISZSPQQHFO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Cp*PtMe2(trifluoromethanesulfonate) 、 potassium p-tolylthiolate 以 四氢呋喃 为溶剂， 以61%的产率得到carbanide;4-methylbenzenethiolate;1,2,3,4,5-pentamethylcyclopenta-1,3-diene;platinum(4+)
  参考文献：
  名称：

  The synthesis of olefin, carbonyl and thiolate complexes of platinum(IV) in the [η5-C5Me5)Pt(IV)] system. Crystal and molecular structure of (η2-C5Me5)PtMe2[S(p-CH3(C6H4]

  摘要：

  A number of Cp*PtMe2X and Cp*PtMe2(L)(+)(OTf)(-) complexes have been prepared [Cp* = eta(5)-C5Me5; OTf = OSO2CF3; X = OTf, I, N-3, S(p-tol); L = CO, C2H4, CH2=CHMe, NH3, NH2But]. The complexes Cp*PtMe2(CO)(+)(OTf)(-), Cp*PtMe2(C2H4)(+)(OTf)(-), and Cp*PtMe2(CH2=CHMe)(+)(OTf)(-) represent a rare type of compound in which a pi acid ligand is coordinated to a high valent metal center predominantly through sigma-donation and pi-backbonding plays only a limited role in the metal-ligand interaction. The arylthiolate complex, Cp*PtMe2[S(p-tol)], has been structurally characterized by X-ray diffraction. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00397-5