| 56968-08-2

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• CAS: 56968-08-2
• 化学式: C19H31NNaO3
• 分子量: 344.4
• InChiKey: LEIPGVJIWXQCHH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.82
• 重原子数：
  24
• 可旋转键数：
  12
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.63
• 拓扑面积：
  60.8
• 氢给体数：
  2
• 氢受体数：
  4

文献信息

• Urethane-modified polyisocyanurate rigid foam
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0222222A1

  公开（公告）日：1987-05-20

  Improved crack-free rigid cellular polyisocyanurate polymers are disclosed that are derived from the reaction of an organic polyisocyanate combination comprising two particular types of polymethylene polyphenyl polyisocyanates (a) and (b), a trimerization catalyst, minor amount of a polyol, a surfactant, and an inert volatile blowing agent having a boil. ing point from about 30°C to about 90°C. The novel rigid foams are particularly useful in preparing high molded bodies of foam by making multiple pours or lifts on top of each other in a mold. The resultant molded body comprises a multiple of molded parts firmly fused to each other and crack-free. Such high molded bodies and process therefor are particularly useful in the insulation of ships.

  本发明公开了改进型无裂纹硬质蜂窝聚异氰酸酯聚合物，该聚合物由有机多异氰酸酯组合物反应制得，该组合物包括两种特定类型的聚亚甲基多苯基多异氰酸酯（a）和（b）、一种三聚催化剂、少量多元醇、一种表面活性剂和一种惰性挥发性发泡剂，发泡剂的沸点约为 30°C 至 90°C。 新型硬质泡沫塑料特别适用于通过在模具中多次浇注或相互提升来制备高模泡沫塑料体。 所得到的模塑体由多个相互牢固融合且无裂纹的模塑件组成。 这种高模泡沫塑料体及其工艺特别适用于船舶绝缘。
• Stabilization of reactivity of polyester polyol based polyurethane foam components
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0283866A1

  公开（公告）日：1988-09-28

  Disclosed are novel polyol blends comprising a polyester polyol, a tertiary amine polyurethane catalyst, and an organic carboxylic acid having a dissociation constant less than 1 x 10⁻³ and which does not readily decarboxylate wherein the carboxylic acid is present in the proportions that its equivalent weight is at least equal to the equivalent weight of the tertiary amine. Also disclosed is the method for stabilizing blends of the above polyester polyols and tertiary amines by adding the carboxylic acid in at least equal equivalent weight to the amine present in the blend. Both polyurethane and polyurethane-polyiso­cyanurate foams prepared from the novel blends are also disclosed.

  公开了新型多元醇混合物，该混合物包含聚酯多元醇、叔胺聚氨酯催化剂和离解常数小于 1 x 10-³且不易脱羧的有机羧酸，其中羧酸的存在比例为其等效重量至少等于叔胺的等效重量。此外，还公开了稳定上述聚酯多元醇和叔胺混合物的方法，即在混合物中加入与胺至少等当量的羧酸。 还公开了用新型混合物制备的聚氨酯和聚氨酯-聚异氰脲酸酯泡沫塑料。
• Rigid polyurethanepolyisocyanurate foams and process for preparing the same
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP0409199A2

  公开（公告）日：1991-01-23

  Disclosed are rigid polyurethane-polyiso­cyanurate foams prepared from polyisocyanates, polyols, trimer catalysts and a blowing agent mixture comprising (i) a halocarbon, and (ii) an organic carboxylic acid, and, optionally water. The foams have excellent aged K-factor values at fluorocarbon levels reduced by up to 75 percent over prior art materials.

  所公开的是由多异氰酸酯、多元醇、三聚体催化剂和发泡剂混合物制备的硬质聚氨酯-聚异氰脲酸酯泡沫，发泡剂混合物包括 (i) 卤化碳和 (ii) 有机羧酸，以及水。 与现有技术材料相比，这些泡沫在碳氟化合物含量降低达 75% 的情况下，具有极佳的老化 K 因子值。
• Crosslinkable polyester/isocyanate compositions suitable for the preparation of composite materials
  申请人：Montedison S.p.A.

  公开号：EP0445837A2

  公开（公告）日：1991-09-11

  Disclosed are crosslinkable polymeric compositions which show a low content of vinyl monomers, are suitable for the fabrication of composite materials having good mechanical properties and comprise: (A)a liquid polyisocyanate; (B)a polyol having a maximum functionality of 7 and an average molecular weight of from about 200 to about 10,000; (C)a vinylester resin or unsaturated polyester resin; (D)a radical polymerization initiator stable at temperatures below 70°C; (E)a decomposition promoter for the initiator (D); (F)a trimerization catalyst for the isocyanate (A); (G)optionally, a mineral filler having dehydrating properties.

  所公开的可交联聚合物组合物中乙烯基单体的含量较低，适用于制造具有良好机械性能的复合材料，其中包括 (A) 液体多异氰酸酯； (B)一种多元醇，其最大官能度为 7，平均分子量约为 200 至 10 000； (C) 乙烯酯树脂或不饱和聚酯树脂； (D) 在低于 70°C 的温度下稳定的自由基聚合引发剂； (E)引发剂(D)的分解促进剂 (F) 异氰酸酯 (A) 的三聚催化剂； (G) 可选的具有脱水特性的矿物填料。
• Crosslinkable polyester/isocyanate compositions suitable for preparing composite manufactured articles, in particular by means of injection processes, process for preparing them and their use
  申请人：SIR INDUSTRIALE S.p.A.

  公开号：EP0570735A2

  公开（公告）日：1993-11-24

  The present invention relates to a crosslinkable polyester/isocyanate composition suitable for preparing composite manufactured articles endowed with high structural mechanical properties, by means of injection processes, comprising: A - a polyfunctional isocyanate; B - an unsaturated polyester resin, or a vinyl ester resin, or a mixture of both said resins, wherein said resin can contain free hydroxy groups; C - a free-radical polymerization initiator; D - a promoter of decomposition of (C) initiator; E - a catalyst of (A) isocyanate trimerization.

  本发明涉及一种可交联聚酯/异氰酸酯组合物，适用于通过注塑工艺制备具有高结构机械性能的复合制成品，该组合物包括 A - 多官能异氰酸酯； B - 不饱和聚酯树脂，或乙烯基酯树脂，或上述两种树脂的混合物，其中所述 树脂可含有游离羟基； C - 自由基聚合引发剂 D - （C）引发剂的分解促进剂； E - (A) 异氰酸酯三聚的催化剂。