1,3,2-dithiastibolan-2-yl morpholine-4-carbodithioate | 149063-89-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 恶嗪烷类
• 英文名称: 1,3,2-dithiastibolan-2-yl morpholine-4-carbodithioate
• CAS: 149063-89-8
• 化学式: C₇H₁₂NOS₄Sb
• 分子量: 376.192
• InChiKey: KNSIRRRGTFZJIR-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14.0
• 可旋转键数：
  1.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.86
• 拓扑面积：
  12.47
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  sodium N-morpholinocarbamodithioate 、 2-Chlor-1.3-dithia-2-stiba-cyclopentan 以 not given 为溶剂， 以60%的产率得到1,3,2-dithiastibolan-2-yl morpholine-4-carbodithioate
  参考文献：
  名称：

  Coordination ability of the heterocycles 1,3-dithia-2-arsa- and -stiba-cyclopentanes towards sulfur containing ligands, part II. Diheterocyclic dithiocarbamate complexes. X-ray structure of the 4-morpholinecarbodithioate of 1,3-dithia-2-arsa-cyclopentane

  摘要：

  A series of diheterocyclic dithiocarbamate complexes of the type RNCS2MS2C2H4, where R = pyrrolidyl, 3-pyrrolyl, 4-morpholyl, 3-methlpiperidyl and M = As or Sb were obtained and characterized by IR, H-1, and C-13-NMR, mass spectroscopy and elemental analyses. The X-ray crystal structure determination of the 4-morpholinecarbodithioate of 1,3-dithia-2-arsa-cyclopentane shows a monodentate behaviour of the RNCS2 entity.

  DOI：

  10.1007/bf00808677