2-(dimethylamino)-3-[2,5-di(2-thienyl)-1H-pyrrol-1-yl]-(2Z)-butene-1,4-dinitrile | 1191251-92-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡咯
• 英文名称: 2-(dimethylamino)-3-[2,5-di(2-thienyl)-1H-pyrrol-1-yl]-(2Z)-butene-1,4-dinitrile
• CAS: 1191251-92-9
• 化学式: C₁₈H₁₄N₄S₂
• 分子量: 350.468
• InChiKey: LRBAGNGLTGXKBB-NXVVXOECSA-N

物化性质

• 熔点：
  128-130 °C
• 沸点：
  472.5±45.0 °C(predicted)
• 密度：
  1.25±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

反应信息

• 作为反应物：
  描述：

  zinc diacetate 、 2-(dimethylamino)-3-[2,5-di(2-thienyl)-1H-pyrrol-1-yl]-(2Z)-butene-1,4-dinitrile 在 1,8-二氮杂双环[5.4.0]十一碳-7-烯 作用下， 以 戊醇 为溶剂， 生成 [2,7,12,18-tetrakis(dimethylamino)-3,8,13,17-tetrakis[2,5-di(2-thienyl)-1H-pyrrol-1-yl]porphyrazinato]zinc(II)
  参考文献：
  名称：

  Synthesis, characterization and spectroscopic properties of novel periphery – functionalized unsymmetrical porphyrazines containing mixed dithienylpyrrolyl and dimethylamino groups

  摘要：

  Following our previous report on a novel class of C(4) symmetric porphyrazines bearing 2,5-dimethylpyrrolyl and methyl(3-pyridylmethyl)amino groups in the periphery, here we report the synthesis and characterization of unsymmetrical porphyrazines with peripheral 2,5-di(2-thienyl)pyrrolyl and dimethylamino groups that break the molecular C4 symmetry. The porphyrazines were prepared via macrocyclization reactions of a dinitrile precursor. Variable-temperature (1)H NMR experiments, single crystal X-ray work and UV-Vis spectra in different solvents of the unsymmetrical magnesium porphyrazine provided information on the structural and electronic features of the entire macrocyclic system. A detailed discussion of the UV-Vis spectra in different solvents emphasizes the role played by the extended peripheral 2,5-di(2-thienyl)pyrrolyl substituent. (C) 2009 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2009.05.033