| 1610941-08-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1610941-08-6
• 化学式: C₂H₇N*C₂₂H₁₈CuN₂O₄*ClHO₄
• 分子量: 583.485
• InChiKey: NRQIKZPHUNVUSP-IRGXHNTLSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  高氯酸 、 monoaqua 3-methoxysalicylaldehyde-o-phenyldiamine copper(II) 、 N,N-二甲基甲酰胺 反应 0.17h， 以75%的产率得到
  参考文献：
  名称：

  Surprising difference between two closely similar O(phenoxo)2O(ether)2 compartments as hosts for an aquated proton and a novel type of host–guest system

  摘要：

  With the aim of checking whether the O(phenoxo)(2)O(methoxy)(2) compartment of 3-methoxysalicylaldehyde-diamine ligands can interact with an aquated proton, the work in this investigation presents the syntheses, characterization, crystal structures and diffuse reflectance spectra of the products obtained from the reactions of three mononuclear copper(II) compounds derived from three H2LOMe ligands (H2LOMe-en, H2LOMe-op and H2LOMe-hex) with perchloric acid in DMF, MeOH and MeOH-MeCN, where 'en', 'op' and 'hex' in the superscripts of the ligand symbols indicate that the diamine functionality comes from ethylenediamine, o-phenylenediamine and trans-1,2-diaminocyclohexane, respectively. From these R reactions, the following six compounds have been isolated: [{(CuLOMe-en)-L-II}(me(2)NH(2))](ClO4) (1), [{(COL)-L-II (OMe-oP))(Me2NH2)](ClO4) (2), [{(CuLOMe-hex)-L-II}(Me2NH2)](ClO4) (3), [{(CuLOMe-en)-L-II}(2)(enH(2))](ClO4)(2) (4, where enH(2) means diprotonated ethylenediamine), [{(CuLOMe-op)-L-II}(2)(opdaH(2))](ClO4)(2)center dot 2H(2)O (5, where enH(2) means diprotonated o-phenylenediamine) and [{(COLOMe-hex)-L-II}(MeOH2)](ClO4) (6). The Me2NH2+ moiety in 1-3, NH3+ sites in 4 and 5 and Me0H; moiety in 6 interact with the 04 compartment by forming bifurcated hydrogen bonds. Interestingly, compound 6 is an unprecedented type of host-guest system. The individual units in 1-6 are self-assembled by non-covalent interactions to generate one, two and three-dimensional self-assemblies. A spectroscopic correlation has been enlightened. (C) 2014 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2014.03.054