[1-methyl-3-butyl-2-methylenimidazoline][bis(2,3,4,5,6-pentafluorophenyl)amine] | 958028-50-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [1-methyl-3-butyl-2-methylenimidazoline][bis(2,3,4,5,6-pentafluorophenyl)amine]
• 英文别名: [BMMIM][BPFPA]；1-n-butyl-2,3-dimethylimidazolium decafluorodiphenyl imide；Bis(2,3,4,5,6-pentafluorophenyl)azanide;1-butyl-2,3-dimethylimidazol-3-ium
• CAS: 958028-50-7
• 化学式: C₉H₁₇N₂*C₁₂F₁₀N
• 分子量: 501.37
• InChiKey: AIHBIUKJNYYUJE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.84
• 重原子数：
  34
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  9.8
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  1-methyl-3-butyl-2-methylenimidazoline 、 1,1'-亚氨基二(2,3,4,5,6-五氟苯) 以 乙醚 为溶剂， 以58%的产率得到[1-methyl-3-butyl-2-methylenimidazoline][bis(2,3,4,5,6-pentafluorophenyl)amine]
  参考文献：
  名称：

  Three novel anions based on pentafluorophenyl amine combined with two new synthetic strategies for the synthesis of highly lipophilic ionic liquids

  摘要：

  本文介绍了 BPFPA、PFTFSI 和 PFNFSI 这三种新的氟化阴离子，它们是高度疏水性、水解稳定的离子液体，同时还介绍了一种策略，可以通过组合方法合成咪唑类和鏻类离子液体，这些离子液体是双四氟酰亚胺（BTFSI）的近亲。

  DOI：

  10.1039/b823153b

文献信息

• Hydrophobic Ionic Liquids
  申请人：Sundermeyer Jorg

  公开号：US20090298189A1

  公开（公告）日：2009-12-03

  The subject of the invention at hand are novel, a little basic, fluorinated pentafluorophenyl imide anions, which can be used as anions in ionic liquids. Methods for producing ionic liquids are described, which contain these novel pentafluorophenyl imide ions as anions, as well as quaternary organic ammonium ions, guanidinium ions, N-organo-pyridinium ions, imidazolium, imidazolidinium or benzimidazolidinium ions, alkyl-alkylidene phosphoranes or aryl-alkylidene phosphoranes as cations. Alternative methods according to the present invention provide ionic liquids through reaction of ketene N,N-diacetals or alkyl or aryl-alkylidene phosphoranes with acids. The ionic liquids according to the present invention are suitable, for example, as solvents for syntheses, as mobile and/or stationary phase in chromatography, as electrolyte systems for batteries, galvanic elements, fuel cells and rechargeable battery packs.

  本发明涉及的主题是新颖、略带基础的氟化五氟苯基亚胺阴离子，可用作离子液体中的阴离子。描述了生产含有这些新型五氟苯基亚胺离子作为阴离子的离子液体的方法，以及含有季铵盐离子、胍盐离子、N-有机吡啶盐离子、咪唑盐、咪唑啉盐或苯并咪唑啉盐、烷基-烷基亚磷烷或芳基-烷基亚磷烷作为阳离子的离子液体。根据本发明的替代方法通过酮N,N-二缩醛或烷基或芳基-烷基亚磷烷与酸反应制备离子液体。根据本发明的离子液体可用作合成溶剂、色谱法中的流动和/或静态相、电池、镀锌元件、燃料电池和可充电电池组的电解质系统。