5,12-bis(4-cyanophenyl)-6,11-diphenyltetracene | 216066-66-9

• 分子结构分类: 有机化合物 - 木脂素、新木脂素和相关化合物 - 芳基萘木脂素
• 英文名称: 5,12-bis(4-cyanophenyl)-6,11-diphenyltetracene
• 英文别名: 4-[12-(4-Cyanophenyl)-6,11-diphenyltetracen-5-yl]benzonitrile
• CAS: 216066-66-9
• 化学式: C₄₄H₂₆N₂
• 分子量: 582.704
• InChiKey: BVABIHGEJJNTQE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.3
• 重原子数：
  46
• 可旋转键数：
  4
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  47.6
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  在 5,12-dihydro-2,3-dimethoxy-5,6,11,12-teraphenyltetracene-5,12-diol 、 氢碘酸 作用下， 以 乙醚 为溶剂， 反应 0.17h， 生成 5,12-bis(4-cyanophenyl)-6,11-diphenyltetracene
  参考文献：
  名称：

  红宝石：平面且扭曲。

  摘要：

  出人意料的是，尽管其在单晶中具有很高的迁移率，但在真空升华或溶液处理的有机薄膜晶体管中，红荧烯的迁移率却非常低。我们合成了几种具有吸电子和供电子取代基的红荧烯类似物，发现大多数取代的红荧烯在固态时不是平面的。此外，我们得出结论（基于实验和计算数据），即使母体红荧烯在溶液和薄膜中也不是平面的。该发现解释了为什么在红荧烯单晶中报道了高迁移率，但是红荧烯在薄膜中显示出非常低的场效应迁移率。在这项工作中获得的取代的红宝石比母红宝石具有更好的溶解性，甚至在溶剂蒸发后甚至形成薄膜而不结晶。因此，

  DOI：

  10.1002/chem.200800802

文献信息

• Aggregate organic light emitting diode devices with improved operational stability
  申请人：Jarikov V. Viktor

  公开号：US20050106415A1

  公开（公告）日：2005-05-19

  An organic light emitting device includes a substrate, an anode and a cathode disposed over the substrate, and a luminescent layer disposed between the anode and the cathode wherein the luminescent layer includes a host and at least one dopant. The host of the luminescent layer is selected to include a solid organic material comprising a mixture of at least two components, one of which contains at least one perylene carbocyclic ring structure or at least one mono-aza-perylene or poly-aza-perylene ring structure and is capable of forming both monomer state and an aggregate state.

  有机发光器件包括基板、位于基板上的阳极和阴极以及位于阳极和阴极之间的发光层，其中发光层包括宿主和至少一种掺杂剂。发光层的宿主被选择为包含至少两种组分的固态有机材料的混合物，其中一种组分包含至少一个苝環烷环结构或至少一个单氮杂苝環或多氮杂苝環环结构，并能够形成单体态和聚集态。
• Organic light-emitting diode devices with improved operational stability
  申请人：Eastman Kodak Company

  公开号：US20040076853A1

  公开（公告）日：2004-04-22

  An organic light-emitting device includes a substrate, an anode and a cathode disposed over the substrate, and a luminescent layer disposed between the anode and the cathode wherein the luminescent layer includes a host and at least one dopant. The host of the luminescent layer is selected to include a solid organic material comprising a mixture of at least two components, one of which is capable of forming both monomer state and an aggregate state.

  一种有机发光器件包括基板、设置在基板上的阳极和阴极，以及设置在阳极和阴极之间的发光层，其中发光层包括宿主和至少一种掺杂剂。发光层的宿主被选择为包括固体有机材料，该材料由至少两种成分的混合物组成，其中一种成分能够形成单体态和集合态。
• OLEDs with improved operational lifetime
  申请人：Klubek P. Kevin

  公开号：US20060040131A1

  公开（公告）日：2006-02-23

  An organic light-emitting device includes a substrate, an anode and a cathode disposed over the substrate, and a light-emitting layer disposed between the anode and the cathode wherein the light-emitting layer includes a host and at least one dopant. The host of the light-emitting layer is selected to include a solid organic material including a mixture of at least two components wherein the first host component is an organic compound capable of transporting electrical charges and also forms an aggregate, and the second component of the mixture is an organic compound capable of transporting electrical charges and, upon mixing with the first host component, is capable of forming a continuous and substantially pin-hole-free layer. The dopant of the light-emitting layer is selected to collect excitons and produce colored light, and an electron-transporting layer is disposed between the light-emitting layer and the cathode for providing improved electron injection and transport.

  一种有机发光器件包括基板、设置在基板上的阳极和阴极，以及设置在阳极和阴极之间的发光层，其中发光层包括宿主和至少一种掺杂剂。发光层的宿主被选择为包括固体有机材料，其中包括至少两种成分的混合物，其中第一宿主成分是一种能够传输电荷的有机化合物，并且还能形成聚集体，混合物的第二成分是一种能够传输电荷的有机化合物，并且在与第一宿主成分混合后，能够形成连续且基本无针孔的层。发光层的掺杂剂被选择用于收集激子并产生彩色光，电子传输层被设置在发光层和阴极之间，用于提供更好的电子注入和传输。
• Hole-trapping materials for improved OLED efficiency
  申请人：Jarikov V. Viktor

  公开号：US20060008672A1

  公开（公告）日：2006-01-12

  An organic light-emitting device includes a light-emitting layer including a host, a dopant, and a hole-trapping material, wherein the hole-trapping material is provided at 0.01 to less than 5% by volume relative to the light-emitting layer volume, has an oxidation potential that is selected so that it is less than the oxidation potential of the host in order to serve as a hole trap, has an oxidation potential that is selected so as to avoid formation of a certain charge transfer complex between the hole-trapping material and the host if the charge transfer complex causes a reduction in the electroluminescent efficiency of the dopant, and has an oxidation potential that is selected so as to avoid formation of the charge transfer complex between the hole-trapping material and the dopant.
• US7183010B2
  申请人：——

  公开号：US7183010B2

  公开（公告）日：2007-02-27